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• W4256299969 abstract "ChemPlusChemVolume 80, Issue 11 p. 1583-1583 InterviewFree Access Vladimir Sindelar First published: 20 October 2015 https://doi.org/10.1002/cplu.201500437AboutSectionsPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract “Science is fun because … it is an adventure with unexpected results.” This and more about Vladimir Sindelar can be found on page 1583. 1 Table 1. Vladimir Sindelar Date of birth: January 6, 1975 Position: Head of Supramolecular Chemistry Group, Masaryk University, Brno, Czech Republic E-mail: sindelar@chemi.mu.cz Homepage: http://www.sci.muni.cz/supramolecular/ Education: 1993–2002: MSc and PhD with Petr Sysel, Institute of Chemical Technology, Prague, Czech Republic; 2002–2003: Postdoctoral Associate with Graeme Cooke, Heriot-Watt University, UK; 2003–2005: Postdoctoral Associate with Angel E. Kaifer, University of Miami, USA. Awards: 2010: Alfred Bader Prize for Organic Chemistry from Czech Academy of Science Current research: Synthesis of supramolecular hosts based on glycoluril including bambusurils, cucurbiturils, and acyclic glycoluril oligomers. Investigation of supramolecular properties of these compounds. Interests: Spending time with my two kids and wife, playing volleyball and squash, travelling. Science is fun because …it is an adventure with unexpected results. I lose track of time when …I try to interpret some experimental data that are somehow unexpected. My favorite molecule is …bambusuril …because …it was discovered in our lab and binds anions with extrordinary strength. My favorite time of day is … early morning, just after I wake up and can decide if I go to work or sleep a little bit longer. What has been your biggest influence/motivation? I should probably mention my parents and grandparents in the first place. They believed in me when I was at basic school and had interests other than school. I was very lucky with my supervisors. My PhD mentor, Petr Sysel, introduced research work to me, Graeme Cooke showed me the beauty of organic synthesis, and Angel E. Kaifer taught me host–guest chemistry. All three gave me freedom with my experimental work which always motivated me to work even harder. How was your research enhanced by taking a multidisciplinary approach? Supramolecular chemistry, which is our field of research, is interdisciplinary in nature. In our lab a project often starts with computational chemistry to visualize the structure of a proposed compound, usually a macrocycle. Subsequently we use the tools of organic chemistry to synthesize the target macrocycle. The prepared macrocycle is characterized by analytical methods including NMR, UV/Vis, and IR spectroscopy and mass spectrometry. These techniques are also necessary to evaluate the supramolecular properties of the compound, specifically to determine the stoichiometry, binding strength, and mode of the complex formed in solution. Finally, we use X-ray crystallography for visualizing the complex in the solid state. What are the main challenges for the future in the broad area of your research? The big challenge for the future is to develop receptors that effectively bind anions not only in organic media but also in water. This will open new applications for these systems in areas such as drug delivery. In cation binding, cucurbiturils proved to be the most potent supramolecular hosts functioning in water. The challenge now is to develop straightforward and reproducible methods for preparing and functionalizing cucurbiturils for commercial application. The researcher presented on this page was nominated for the Early Career Series by Prof. Dr. Michal Hocek. His most recent paper is featured on the Front Cover of this issue. “Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform”: V. Havel, V. Sindelar, ChemPlusChem 2015, 80, 1601. My three top papers: References 1J. Svec, M. Necas, V. Sindelar, “Bambus[6]uril”: Angew.Chem. Int. Ed. 2010, 49, 2378–2381; Angew. Chem. 2010, 122, 2428–2431. (Discovery of a novel macrocycle with the ability to strongly bind anions.) Google Scholar 2M. A. Yawer, V. Havel, V. Sindelar, “A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity”: Angew.Chem. Int. Ed. 2015, 54, 276–279; Angew. Chem. 2015, 127, 278–281. (We reported that bambusurils are the most potent neutral receptors for many inorganic anions in water.) Google Scholar 3L. Gilberg, M. S. A. Khan, M. Enderesova, V. Sindelar, “Cucurbiturils Substituted on the Methylene Bridge”: Org. Lett., 2014, 16, 2446–2449. (First example of cucurbituril substituted on one methylene bridge.) Google Scholar Volume80, Issue11November 2015Pages 1583-1583 ReferencesRelatedInformation" @default.
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