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• W4256306089 abstract "Abstract We describe herein formal syntheses of the indole alkaloids cis ‐trikentrin A and herbindole B from a common meso ‐hydroquinone intermediate prepared by a ruthenium‐catalyzed [2+2+1+1] cycloaddition that has not been used previously in natural product synthesis. Key steps include a sterically demanding Buchwald–Hartwig amination as well as a unique C(sp 3 )−H amination/indole formation. Studies toward a selective desymmetrization of the meso ‐hydroquinone are also reported." @default.
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• W4256306089 date "2016-08-29" @default.
• W4256306089 modified "2023-09-27" @default.
• W4256306089 title "Application of a Palladium‐Catalyzed C−H Functionalization/Indolization Method to Syntheses of <i>cis</i>‐Trikentrin A and Herbindole B" @default.
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• W4256306089 doi "https://doi.org/10.1002/ange.201605475" @default.
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