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- W4256306989 abstract "The crystal structure of trichlorobis-(o-methoxyphenyldimethylarsine)rhodium(III), RhCl3 oas2(oas =o-methoxyphenyldimethylarsine) has been determined by three-dimensional X-ray diffraction techniques and refined by least-squares calculations to R 0·10 for 1401 observed reflexions. The crystals are orthorhombic, space group P212121, with Z= 4, and a= 9·077 ± 0·012, b= 15·218 ± 0·03, and c= 16·954 ± 0·03 Å. The structure consists of discrete molecules. A distorted octahedral arrangement around the rhodium atom is realized by three mutually cis chlorine atoms, two mutually cis arsenic atom, and one oxygen atom trans to the arsenic atom of the other ligand, the oxygen atom of which is not co-ordinated. All the Cl–Rh and As–Rh distances lie in the range 2·33 to 2·39 Å. The O–Rh bond-length is 2·24 Å. l.r. spectra in the 350 cm.–1 region indicate that the longest Rh–Cl bond is broken when the complex is treated with silver nitrate in methanol to give the trans-octahedral product [RhCl2 oas2]Cl." @default.
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- W4256306989 date "1969-01-01" @default.
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- W4256306989 title "Structural investigations on rhodium(III) complexes. Part I. Crystal structure of trichlorobis-(o-methoxyphenyldimethylarsine)rhodium(III)" @default.
- W4256306989 doi "https://doi.org/10.1039/j19690001236" @default.
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