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• W4256359350 abstract "[20717-86-6] C9H24ClO3Ti (MW 260.62) InChI = 1S/3C3H7O.ClH.Ti/c3*1-3(2)4;;/h3*3H,1-2H3;1H;/q3*-1;;+4/p-1 InChIKey = IFMWVBVPVXRZHE-UHFFFAOYSA-M (mild Lewis acid used for the preparation of organotitanium derivatives1 and titanium enolates;1, 2 alkyl, 3-5 allyl,3, 4, 6 aryl,3-5 alkenyl,7 allenyl,8 and alkynyl9, 10 titanium triisopropoxides exhibit reduced basicity and add to carbonyl compounds with enhanced chemo-, regio-, and stereoselectivity;1b–f titanium enolates2 react with aldehydes and imines11 with high levels of syn selectivity12 and greatly enhanced diastereofacial selectivity;13 titanium isopropoxides mediate the regioselective opening of epoxides14, 15 and serve as a titanium source for the preparation of chiral titanium complexes16) Alternate Names: chlorotitanium tris(isopropoxide); chlorotriisopropoxytitanium; chlorotris(2-propanolato)titanium. Physical Data: mp 45–50 °C; bp 61–65 °C/0.1 mmHg; d 1.091 g cm−3. Solubility: sol most nonprotic organic solvents, e.g. Et2O, THF, CH2Cl2, toluene, hexanes. Form Supplied in: syrupy liquid; 1.0 M solution in CH2Cl2 or hexanes. Preparative Method: available commercially, but can be easily made from a 3∶1 mixture of Titanium Tetraisopropoxide and Titanium(IV) Chloride,3 which can be distilled to give the pure reagent or used in situ.17 Handling, Storage, and Precautions: corrosive; moisture sensitive; flammable liquid; can be stored under nitrogen, in pure form or in solution, for months." @default.
• W4256359350 created "2022-05-12" @default.
• W4256359350 creator A5014830806 @default.
• W4256359350 creator A5040956821 @default.
• W4256359350 creator A5091518989 @default.
• W4256359350 date "2007-09-17" @default.
• W4256359350 modified "2023-09-25" @default.
• W4256359350 title "Chlorotitanium Triisopropoxide" @default.
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