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- W4256374962 abstract "Der richtige Dreh: Nicht oft wird nach experimentellen Belegen für relativistische Effekte auf den Tensor der chemischen Verschiebung in der Festkörper-NMR-Spektroskopie gesucht. 29Si-MAS-NMR-spektroskopische Messungen mit langsamer Rotation (MAS=Rotation im magischen Winkel) an der Triade [ClTM(μ-mt)4SiCl] (TM=Pt, Pd, Ni; mt=2-Mercapto-1-methylimidazolid) zeigten, dass die Schweratom-Spin-Bahn-Kopplung die Form des 29Si-NMR-Signals stark beeinflusst. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4256374962 date "2010-11-29" @default.
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- W4256374962 title "<sup>29</sup> Si DFT/NMR Observation of Spin–Orbit Effect in Metallasilatrane Sheds Some Light on the Strength of the Metal→Silicon Interaction" @default.
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