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- W4256376220 abstract "The first neo-confused hexaphyrin(1.1.1.1.1.0) was synthesized by oxidative ring closure of a hexapyrrane bearing two terminal “confused” pyrroles. The new compound displays a folded conformation with a short interpyrrolic C⋅⋅⋅N distance of 3.102 Å, and thus it readily underwent ring fusion to afford a neo-fused hexaphyrin with an unprecedented 5,5,5,7-tetracyclic ring structure. Furthermore, coordination of CuII triggered a ring opening/contracting reaction to afford a CuII complex of an N-linked pentaphyrin derivative. The roles of reactive NC bonds in the porphyrinoid macrocycles were demonstrated." @default.
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- W4256376220 date "2014-10-16" @default.
- W4256376220 modified "2023-10-18" @default.
- W4256376220 title "Neo-Fused Hexaphyrin: A Molecular Puzzle Containing an N-Linked Pentaphyrin" @default.
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- W4256376220 doi "https://doi.org/10.1002/ange.201408307" @default.
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