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- W4256397768 abstract "The crystals of 5,5′-dibromo-3-diethylaminomethyl-2,2′-biphenol N-oxide were studied by X-ray and FT-IR spectroscopy. Within this molecule two short OHO intramolecular hydrogen bonds are formed. The NO⋯H+⋯O− bond between the OH and the N-oxide groups is very strong, of 2.419(7) Å between the oxygen atoms. The proton potential of this hydrogen bond is flat, broad and has probably no barrier—consequently it could not be located from X-ray diffraction data. The other hydrogen bond formed between two hydroxyl groups appears asymmetrical from FT-IR spectra, and shows also relatively limited proton polarizability. The molecular conformation is non-planar, due to strong overcrowding effect between the oxygen atoms involved in the hydrogen bonds." @default.
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- W4256397768 date "2002-06-01" @default.
- W4256397768 modified "2023-10-18" @default.
- W4256397768 title "Shape of the proton potential in an intramolecular hydrogen-bonded system. Part II" @default.
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- W4256397768 doi "https://doi.org/10.1016/s0022-2860(02)00074-1" @default.
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