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- W4256445445 abstract "<div>Noble metal foams (NMFs) are a new class of functional porous materials featuring properties of both noble metals and monolithic porous materials, providing impressive prospects in catalysis, bio-sensing, plasmonic technologies, etc...Among reported synthetic methods to date, the sol-gel approach manifests overwhelming advantages for versatile synthesis of controlled nanostructured NMFs under mild condition. However, limited gelation methods and insufficient understanding of the underlying mechanism retards structure/composition manipulation of NMFs, hampering ondemand designing for practical applications. Herein highly tunable NMFs are fabricated at room temperature by activating specific-ion effects and regulating ion-nanoparticle interactions, affording various single/alloy NMFs with adjustable compositions (Au, Ag, Pd, Pt), ligament sizes (3.1~142.0 nm), and special morphologies. Their superior performance in programmable self-propulsion devices and electrocatalytic alcohol oxidation are demonstrated. This study provides not only a conceptually new route to fabricate and manipulate functional NMFs, but also an overall picture in understanding the gelation mechanism. It may pave the way for on-target designing versatile NMFs for various applications.</div>" @default.
- W4256445445 created "2022-05-12" @default.
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- W4256445445 date "2019-03-13" @default.
- W4256445445 modified "2023-09-28" @default.
- W4256445445 title "Specific-Ion Effects Directed Noble Metal Aerogels: Versatile Manipulation for Electrocatalysis and Beyond" @default.
- W4256445445 doi "https://doi.org/10.26434/chemrxiv.7823702.v1" @default.
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