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- W4256464058 abstract "We report a novel sol–gel dip-coating process to form dual-layer microporous silica membranes with improved membrane performance and reproducibility. First, we deposit a surfactant-templated silica (STS) intermediate layer on top of a commercial γ-alumina support both to improve its ‘surface finish’ and to prevent a subsequently deposited microporous overlayer from penetrating into the support. Second, membranes are processed under clean room conditions to avoid dust contamination, and third, membranes are vacuum-calcined to promote further pore shrinkage and impart surface hydrophobicity. The resulting asymmetric membrane exhibits a gradual change in pore diameter from 50 Å (γ-alumina support layer) to 10–12 Å (STS intermediate layer), and then to 3–4 Å (30 nm thick, ultramicroporous silica top-layer). Compared to a single-layer process using only the microporous overlayer, the dual-layer process improves both flux and selectivity. For the industrially important problem of natural gas purification, the combined CO2 flux ((3–0.5)×10−4 cm3(STP)/s/cm2/cm Hg) and CO2/CH4 separation factors (200–600) are superior to all previously reported values for the separation of a 50/50 (v/v) CO2/CH4 gas mixture. In addition, the membrane selectively separated hydrogen from a simulated reformate from partial oxidation of methanol as evidenced by a high concentration of hydrogen recovery." @default.
- W4256464058 created "2022-05-12" @default.
- W4256464058 date "2000-03-01" @default.
- W4256464058 modified "2023-09-25" @default.
- W4256464058 title "00/01119 Ventilation of gas accumulating areas" @default.
- W4256464058 doi "https://doi.org/10.1016/s0140-6701(00)91096-8" @default.
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