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- W4256568968 abstract "The gas-phase equilibria of solvation reactions of N+2 and O+2 ions with N2 were measured with a pulsed electron-beam high-pressure mass spectrometer. van’t Hoff plots of the equilibrium constants lead to the determination of the thermochemical stabilities for N+2(N2)n and O+2(N2)n clusters with n=1–11. While a covalent bond was formed in the cluster N+2⋅⋅⋅N2, the interaction is largely electrostatic for ligands in the clusters N+2(N2)n with n=2–11. The decrease in the −ΔH0n−1,n values of N+2(N2)n with n for n=2→11 are rather smooth, i.e., the clusters N+2(N2)n do not have any particularly stable shell structures except for n=1. On the contrary, O+2(N2)n was found to have the shell structure with n=4." @default.
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- W4256568968 date "1988-06-15" @default.
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- W4256568968 title "A determination of the stabilities of N<sup>+</sup><sub>2</sub>(N<sub>2</sub>)<sub><i>n</i></sub> and O<sup>+</sup><sub>2</sub>(N<sub>2</sub>)<sub><i>n</i></sub> with <i>n</i>=1–11 from measurements of the gas‐phase ion equilibria" @default.
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- W4256568968 doi "https://doi.org/10.1063/1.454285" @default.
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