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- W42587347 abstract "Rates of HF(v = 3) removal by H and D atoms were measured between 200 and 295 K in a laser-induced fluorescence-discharge flow-tube apparatus. The removal rates by H atoms were found to increase from 6.3 x 10 to the 13th power cu. cm/mol-sec at 295 K to 10 to the 14th power cu. cm/mol-sec at 200 K. The removal of HF(v = 3) by D atoms is somewhat slower, but the removal rates have a similar negative temperature dependence. There are several mechanisms by which H atoms can remove HF(v = 3), i.e., reaction to form H/sub 2/ + F or deactivation to HF(v = 0, 1, or 2) with or without exchange of the F atom. The several possibilities are discussed and compared to theoretical calculations." @default.
- W42587347 created "2016-06-24" @default.
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- W42587347 date "1978-01-27" @default.
- W42587347 modified "2023-09-24" @default.
- W42587347 title "Kinetic study of h + hf(v = 3); kinetic isotope effect and temperature dependence. Interim report" @default.
- W42587347 hasPublicationYear "1978" @default.
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