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- W42710193 abstract "The reaction of carbenes or carbenoid species (CH2,CBr2,CClMe) with silyl enol ethers leads to silyloxycyclopropanes and easy ring opening of these products yields various interesting carbonyl compounds. An account of the recent literature in the field is given and the main results obtained in the Laboratoire des Carbocycles at Orsay are reported. The halocarbenes CBr2 and CClMe lead to unsaturated carbonyl compounds because ring opening always occurs with the elimination of XSiMe3. Ring enlargement of cycloalkanones into higher 2-methyl-cycloalkenones and the direct preparation of E and (or) Z αβ-ethylenic ketones and aldehydes from the appropriate halo-silyloxycyclopropane isomers, without Z → E isomerisation, are discussed in greater detail." @default.
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- W42710193 date "1983-01-01" @default.
- W42710193 modified "2023-10-03" @default.
- W42710193 title "REACTION OF SILYL ENOL ETHERS WITH CARBENES AND CARBENOIDS. NEW SYNTHESES OF VARIOUS CARBONYL COMPOUNDS" @default.
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- W42710193 doi "https://doi.org/10.1016/b978-0-08-029217-5.50033-4" @default.
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