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• W42726821 abstract "This chapter concerns applications of “organometallic clusters” in the period 1993 to mid-2005. These applications include homogeneous catalysis, precursors for or models of heterogeneous metal catalysts, nanoparticle precursors, biomedical imaging, and optical materials. One definition of a metal cluster is “a molecular compound containing three or more metals in a closed array, and held together by metal–metal bonds.” This definition focused on the importance of the metal–metal interactions, and the unique structural features presented by closed metal arrays. However, this definition has been considerably broadened by common usage. Compounds containing only two metal atoms, compounds containing several metal atoms held together by bridging ligands and without metal–metal bonds, or even small metal particles are commonly referred to as “metal clusters.” Through the years 1970–1990, most applications of organometallic clusters concerned catalysis, either as homogeneous catalysts or as precursors for heterogeneous catalysts. Since these two applications have been extensively reviewed and since homogeneous catalysis is treated elsewhere, the stricter definition of a metal cluster was used: a metal cluster is a molecular compound of three or more metal atoms in a closed array and having a substantial metal–metal interaction. More recently, clusters have been examined as precursors for nanoscale materials, as biomedical imaging agents, and as optical materials. For these newer applications, the broadest definition of a metal cluster has been used, including compounds containing several metal atoms held together by bridging ligands and without metal–metal bonds, or even small metal particles if the particles are stabilized by a ligand shell rather than a heterogeneous support." @default.
• W42726821 created "2016-06-24" @default.
• W42726821 creator A5018970120 @default.
• W42726821 date "2007-01-01" @default.
• W42726821 modified "2023-09-26" @default.
• W42726821 title "Organometallic Clusters" @default.
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