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- W4280492327 abstract "A novel porous membrane based on pyridinium-functionalized poly(phthalazinone ether ketone) with pendant phenyl groups (PyPPEK-P) is synthesized from poly(phthalazinone ether ketone) with benzyl chloride moieties by the vapor induced phase separation (VIPS) process. The membrane is used for vanadium redox flow batteries (VRFB). Pyridine is used as an amination reagent to improve the chemical stability of the membrane, and its successful introduction is experimentally confirmed. The structure and properties of the porous membrane are adjusted by VIPS to enhance the membrane performance when used in batteries. It is found that a lower temperature and a longer exposure time are beneficial to obtaining a large pore size in cross-section, while relative humidity exert a complex effect on the membrane structure. The PyPPEK-P membrane prepared by mixed NMP and DMAc solvents as casting solution exhibit the best battery performance. Compared with Nafion 115, the PyPPEK-P membrane display higher coulombic efficiency (97.2% vs. 96.8%), voltage efficiency (83.1% vs. 76.9%), and energy efficiency (81.0% vs. 76.8%) at a 140 mA cm−2 current density. After 1000 charge-discharge cycles, the PyPPEK-P membrane exhibit a low capacity-decay, while the battery performance do not decline. These observations indicate that PyPPEK-P porous membranes have good application prospects in VRFB." @default.
- W4280492327 created "2022-05-22" @default.
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- W4280492327 date "2022-08-01" @default.
- W4280492327 modified "2023-10-16" @default.
- W4280492327 title "Pyridinium functionalized poly(phthalazinone ether ketone) with pendant phenyl groups porous membranes for vanadium flow battery application by vapor induced phase separation" @default.
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- W4280492327 doi "https://doi.org/10.1016/j.memsci.2022.120646" @default.
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