Matches in SemOpenAlex for { <https://semopenalex.org/work/W4280494543> ?p ?o ?g. }
- W4280494543 endingPage "11431" @default.
- W4280494543 startingPage "11369" @default.
- W4280494543 abstract "Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding molecular orbital (NBMO), which originates from the linear combination of atomic orbitals (LCAO) arising from 13 carbon atoms of the phenalenyl molecule. Three redox states (cationic, neutral radical, and anionic) of the phenalenyl-based molecules were attributed to the presence of this NBMO. The cationic state can undergo two consecutive reductions to result in neutral radical and anionic states, stepwise, respectively. The phenalenyl-based radicals were found as crucial building blocks and attracted the attention of various research fields such as organic synthesis, material science, computation, and device physics. From 2012 onward, a strategy was devised using the cationic state of phenalenyl-based molecules and in situ generated phenalenyl radicals, which created a new domain of catalysis. The in situ generated phenalenyl radicals were utilized for the single electron transfer (SET) process resulting in redox catalysis. This emerging range of applications rejuvenates the more than six decades-old phenalenyl chemistry. This review captures such developments ranging from fundamental understanding to multidirectional applications of phenalenyl-based radicals." @default.
- W4280494543 created "2022-05-22" @default.
- W4280494543 creator A5071640196 @default.
- W4280494543 creator A5090045177 @default.
- W4280494543 date "2022-05-13" @default.
- W4280494543 modified "2023-10-09" @default.
- W4280494543 title "Phenalenyl Radical: Smallest Polycyclic Odd Alternant Hydrocarbon Present in the Graphene Sheet" @default.
- W4280494543 cites W1155152291 @default.
- W4280494543 cites W1473592756 @default.
- W4280494543 cites W1491547903 @default.
- W4280494543 cites W1565925540 @default.
- W4280494543 cites W1649004299 @default.
- W4280494543 cites W1764892412 @default.
- W4280494543 cites W1923966092 @default.
- W4280494543 cites W1959464420 @default.
- W4280494543 cites W1965173894 @default.
- W4280494543 cites W1965931896 @default.
- W4280494543 cites W1966789167 @default.
- W4280494543 cites W1967285535 @default.
- W4280494543 cites W1967695375 @default.
- W4280494543 cites W1967715923 @default.
- W4280494543 cites W1968199513 @default.
- W4280494543 cites W1971499434 @default.
- W4280494543 cites W1973002195 @default.
- W4280494543 cites W1974551199 @default.
- W4280494543 cites W1974607002 @default.
- W4280494543 cites W1975883386 @default.
- W4280494543 cites W1976820714 @default.
- W4280494543 cites W1976849993 @default.
- W4280494543 cites W1977462067 @default.
- W4280494543 cites W1977511744 @default.
- W4280494543 cites W1977953300 @default.
- W4280494543 cites W1978903117 @default.
- W4280494543 cites W1980197072 @default.
- W4280494543 cites W1980363159 @default.
- W4280494543 cites W1980797602 @default.
- W4280494543 cites W1981238142 @default.
- W4280494543 cites W1981295956 @default.
- W4280494543 cites W1983998320 @default.
- W4280494543 cites W1984552842 @default.
- W4280494543 cites W1984697143 @default.
- W4280494543 cites W1985002018 @default.
- W4280494543 cites W1985088132 @default.
- W4280494543 cites W1985545604 @default.
- W4280494543 cites W1985570466 @default.
- W4280494543 cites W1985652286 @default.
- W4280494543 cites W1988382080 @default.
- W4280494543 cites W1988515085 @default.
- W4280494543 cites W1988957402 @default.
- W4280494543 cites W1989471615 @default.
- W4280494543 cites W1989785757 @default.
- W4280494543 cites W1990879541 @default.
- W4280494543 cites W1993886668 @default.
- W4280494543 cites W1995606776 @default.
- W4280494543 cites W1996754920 @default.
- W4280494543 cites W1998767752 @default.
- W4280494543 cites W1999115975 @default.
- W4280494543 cites W2000043459 @default.
- W4280494543 cites W2000800381 @default.
- W4280494543 cites W2000865549 @default.
- W4280494543 cites W2001131432 @default.
- W4280494543 cites W2001639635 @default.
- W4280494543 cites W2001908875 @default.
- W4280494543 cites W2002629749 @default.
- W4280494543 cites W2003794153 @default.
- W4280494543 cites W2005010844 @default.
- W4280494543 cites W2005445352 @default.
- W4280494543 cites W2005510376 @default.
- W4280494543 cites W2005562487 @default.
- W4280494543 cites W2005877813 @default.
- W4280494543 cites W2005937895 @default.
- W4280494543 cites W2006557486 @default.
- W4280494543 cites W2008708918 @default.
- W4280494543 cites W2009195137 @default.
- W4280494543 cites W2009857519 @default.
- W4280494543 cites W2010106384 @default.
- W4280494543 cites W2010999932 @default.
- W4280494543 cites W2012554369 @default.
- W4280494543 cites W2014826538 @default.
- W4280494543 cites W2014935324 @default.
- W4280494543 cites W2016138580 @default.
- W4280494543 cites W2017473864 @default.
- W4280494543 cites W2018103807 @default.
- W4280494543 cites W2018855005 @default.
- W4280494543 cites W2019770822 @default.
- W4280494543 cites W2020599822 @default.
- W4280494543 cites W2021572700 @default.
- W4280494543 cites W2021932368 @default.
- W4280494543 cites W2023103067 @default.
- W4280494543 cites W2023246165 @default.
- W4280494543 cites W2023949702 @default.
- W4280494543 cites W2024661914 @default.
- W4280494543 cites W2024747980 @default.
- W4280494543 cites W2024839715 @default.
- W4280494543 cites W2026238435 @default.
- W4280494543 cites W2026729555 @default.
- W4280494543 cites W2026796332 @default.
- W4280494543 cites W2026947394 @default.