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- W4280495628 abstract "Abstract The changes in intermetallic phases of Mg-6%Al-5%Pb (Mg-Al-Pb) alloy prepared by powder metallurgy and their effects on electrochemical properties were studied. Experimental results showed that coarse Mg 17 Al 12 phases (with size ranges from 20 μ m to 70 μ m) and fine Mg 2 Pb phases (with the size of 100 nm scale) formed in the mixed Al, Pb and Mg powder during the hot press sintering procedure. Fine Mg 2 Pb phases exhibit strong diffusional ability to diffuse into Mg 17 Al 12 phases. Extruding further promotes the diffusion of Mg 2 Pb phases into Mg 17 Al 12 phases. Solution treatment produced a mixed microstructure which is Mg 17 Al 12 phase containing Mg 2 Pb phases inside and made other Mg 2 Pb phases homogeneously distributed in Mg matrix. Mg 17 Al 12 phases and the gathered Mg 2 Pb phases will accumulate the Mg(OH) 2 corrosion products, which impedes the subsequent discharge behavior. Homogeneously distributed Mg 2 Pb phases will fall off during discharge, which makes the discharge curve more stable. The mixed microstructure has positive effect on corrosion resistance and discharge potential. Therefore, solution-treated alloy shows the highest negative potential and the smoothest curve during the galvanostatic discharge test. Compared with the commercial AZ61 sheet, solution-treated alloy exhibit much higher anode properties in Mg/PbCl 2 battery test. Thus, the solution-treated alloy could serve as an excellent anode in seawater-activated batteries." @default.
- W4280495628 created "2022-05-22" @default.
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- W4280495628 date "2022-06-01" @default.
- W4280495628 modified "2023-10-13" @default.
- W4280495628 title "Effects of intermetallic phases on electrochemical properties of powder metallurgy Mg-6%Al-5%Pb anode alloy used for seawater activated battery" @default.
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- W4280495628 doi "https://doi.org/10.1088/2053-1591/ac703c" @default.
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