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• W4280496024 endingPage "7135" @default.
• W4280496024 startingPage "7124" @default.
• W4280496024 abstract "Herein, we reported a so far unprecedented Mn(OAc)3·2H2O-promoted homolytic aromatic sulfonation. The reaction was performed under mild conditions with K2S2O5 employed as a green sulfonating reagent. Various arenes were successfully converted into desired sulfonic acids or sulfonates in high efficiency. Preliminary mechanistic studies demonstrated that the present reaction proceeds via a homolytic aromatic substitution-type mechanism involving an SO3- radical. The combination of Mn(OAc)3·2H2O and HFIP plays a crucial role." @default.
• W4280496024 created "2022-05-22" @default.
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• W4280496024 date "2022-05-18" @default.
• W4280496024 modified "2023-10-01" @default.
• W4280496024 title "Homolytic Aromatic Sulfonation with K₂S₂O₅ Promoted by a Combination of Mn(OAc)₃·2H₂O and HFIP" @default.
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• W4280496024 doi "https://doi.org/10.1021/acs.joc.2c00321" @default.
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