Matches in SemOpenAlex for { <https://semopenalex.org/work/W4280497577> ?p ?o ?g. }
- W4280497577 abstract "CO2 dissolved in aqueous solutions CO2(aq) is important to CO2 capture, storage, photo-/electroreduction in the fight against global warming and to CO2 analysis in drinks. Here, we developed microscale infrared (IR) spectroscopy for in situ dynamic quantitating CO2(aq). The quantized CO2(g) rotational state transitions were observed to quench for CO2(aq), accompanied by increased H2O IR absorption. An accurate CO2 molar extinction coefficient ε was derived for in situ CO2(aq) quantification up to 58 atm. We directly measured CO2(aq) concentrations in electrolytes under CO2(g) bubbling and high-pressure conditions with high spectral and time resolutions. In KHCO3 electrolytes with CO2(aq) > ~1 M, CO2 electroreduction (CO2RR) to formate reached >98% Faradaic efficiencies on copper (Cu2O/Cu)-based electrocatalyst. Furthermore, CO2 dissolution/desolvation kinetics showed large hysteresis and ultraslow reversal of CO2(aq) supersaturation in aqueous systems, with implications to CO2 capture, storage, and supersaturation phenomena in natural water bodies." @default.
- W4280497577 created "2022-05-22" @default.
- W4280497577 creator A5031185515 @default.
- W4280497577 creator A5059252660 @default.
- W4280497577 creator A5065034148 @default.
- W4280497577 date "2022-05-13" @default.
- W4280497577 modified "2023-10-16" @default.
- W4280497577 title "Probing dissolved CO<sub>2</sub>(aq) in aqueous solutions for CO<sub>2</sub>electroreduction and storage" @default.
- W4280497577 cites W137242621 @default.
- W4280497577 cites W1907188557 @default.
- W4280497577 cites W1966666234 @default.
- W4280497577 cites W1970961051 @default.
- W4280497577 cites W1975747146 @default.
- W4280497577 cites W1978610137 @default.
- W4280497577 cites W1981315483 @default.
- W4280497577 cites W1981368803 @default.
- W4280497577 cites W1984211402 @default.
- W4280497577 cites W1990720017 @default.
- W4280497577 cites W1991502202 @default.
- W4280497577 cites W1992941103 @default.
- W4280497577 cites W2014508778 @default.
- W4280497577 cites W2022230035 @default.
- W4280497577 cites W2034814660 @default.
- W4280497577 cites W2035616341 @default.
- W4280497577 cites W2044390388 @default.
- W4280497577 cites W2045479559 @default.
- W4280497577 cites W2046033784 @default.
- W4280497577 cites W2049407323 @default.
- W4280497577 cites W2049564519 @default.
- W4280497577 cites W2055563809 @default.
- W4280497577 cites W2057042736 @default.
- W4280497577 cites W2065757473 @default.
- W4280497577 cites W2068366103 @default.
- W4280497577 cites W2070090119 @default.
- W4280497577 cites W2073328513 @default.
- W4280497577 cites W2075597882 @default.
- W4280497577 cites W2077975305 @default.
- W4280497577 cites W2078790853 @default.
- W4280497577 cites W2085167193 @default.
- W4280497577 cites W2085765714 @default.
- W4280497577 cites W2096747776 @default.
- W4280497577 cites W2098453150 @default.
- W4280497577 cites W2126079425 @default.
- W4280497577 cites W2128687341 @default.
- W4280497577 cites W2138830031 @default.
- W4280497577 cites W2147428684 @default.
- W4280497577 cites W2154062353 @default.
- W4280497577 cites W2161931994 @default.
- W4280497577 cites W2171971882 @default.
- W4280497577 cites W2173001546 @default.
- W4280497577 cites W2204581405 @default.
- W4280497577 cites W2223147105 @default.
- W4280497577 cites W2239994365 @default.
- W4280497577 cites W2253015770 @default.
- W4280497577 cites W2295560549 @default.
- W4280497577 cites W2318643106 @default.
- W4280497577 cites W2319195884 @default.
- W4280497577 cites W2322060739 @default.
- W4280497577 cites W2327587770 @default.
- W4280497577 cites W2328105223 @default.
- W4280497577 cites W2328636165 @default.
- W4280497577 cites W2474703360 @default.
- W4280497577 cites W2509265340 @default.
- W4280497577 cites W2588520044 @default.
- W4280497577 cites W2749876395 @default.
- W4280497577 cites W2754478583 @default.
- W4280497577 cites W2766486606 @default.
- W4280497577 cites W2767138048 @default.
- W4280497577 cites W2772769038 @default.
- W4280497577 cites W2804235153 @default.
- W4280497577 cites W2892106384 @default.
- W4280497577 cites W2894609865 @default.
- W4280497577 cites W2903681646 @default.
- W4280497577 cites W2906621703 @default.
- W4280497577 cites W2913379862 @default.
- W4280497577 cites W2940516743 @default.
- W4280497577 cites W2985601352 @default.
- W4280497577 cites W2990481474 @default.
- W4280497577 cites W3013270106 @default.
- W4280497577 cites W3014132988 @default.
- W4280497577 cites W3015483136 @default.
- W4280497577 cites W3132072414 @default.
- W4280497577 cites W4300020856 @default.
- W4280497577 cites W650708343 @default.
- W4280497577 doi "https://doi.org/10.1126/sciadv.abo0399" @default.
- W4280497577 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35559679" @default.
- W4280497577 hasPublicationYear "2022" @default.
- W4280497577 type Work @default.
- W4280497577 citedByCount "11" @default.
- W4280497577 countsByYear W42804975772022 @default.
- W4280497577 countsByYear W42804975772023 @default.
- W4280497577 crossrefType "journal-article" @default.
- W4280497577 hasAuthorship W4280497577A5031185515 @default.
- W4280497577 hasAuthorship W4280497577A5059252660 @default.
- W4280497577 hasAuthorship W4280497577A5065034148 @default.
- W4280497577 hasBestOaLocation W42804975772 @default.
- W4280497577 hasConcept C107872376 @default.
- W4280497577 hasConcept C113196181 @default.
- W4280497577 hasConcept C147789679 @default.
- W4280497577 hasConcept C161790260 @default.