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• W4280497757 abstract "Copper (Cu) is the most efficient metal that can electrochemically convert CO 2 to various chemical feedstocks at reasonable efficiency. The activity and selectivity toward the CO 2 reduction reaction (CO 2 RR) largely depend on the surface sensitivity and electrokinetics of Cu catalysts. Surface engineering is achievable through tuning the structure and through crystal orientation. The Cu-surface modulation and tunings, e.g., controlled morphology, oxygen vacancies, and alloys on supports or substrates, propose different reaction tracks and intermediates, whereas common routes are ∗CO dimerization, C–C, and C 1 –C 2 coupling for the formation of C 2 and C 3 products. In this review, recent progress on the surface engineering of Cu-based catalysts is primarily recaptured and explained. The fragmentation, coalescence, and aggregation of Cu nanoparticles cause stability issues of Cu catalysts during the CO 2 RR, which has also been discussed. Finally, we summarize critical strategies and approaches to surface engineering of Cu-based catalysts for the efficient CO 2 RR. The continuous depletion of fossil fuels is the leading cause of global climate change due to the large accumulation of carbon dioxide (CO 2 ) in the atmosphere. Electrochemical CO 2 reduction into valuable products of fuels and chemicals would be a promising technical approach, and this relies on efficient electrocatalysts to accelerate CO 2 reduction reaction (CO 2 RR) and alleviate the energy crisis. As the most efficient metal, copper (Cu) has been widely explored for the CO 2 RR. However, a grand challenge for an ideal Cu-based catalyst is low faradaic efficiency (FE) for C 2+ products, and this highlights the CO 2 RR dependence and sensitivity to the surface of Cu catalysts. This review systematically summarizes the strategies for surface engineering of Cu catalysts and their effects on catalytic selectivity and activity for the CO 2 RR, which will have a substantial impact on the field to achieve the targets for commercial applications of CO 2 RR processes. Surface engineering is crucial to enhance the selectivity and activity for the efficient CO 2 reduction reaction (CO 2 RR) to a particular C 2+ product. This review recaptures recent progress on the surface engineering of Cu-based catalysts as the most extensively studied metal for the CO 2 RR, holding the great promise of neutralizing the carbon in the environment. Furthermore, how the optimized surface, phase effects, morphology, and configuration influence the catalytic performance and the reasons for Cu catalysts' instability are also discussed." @default.
• W4280497757 created "2022-05-22" @default.
• W4280497757 creator A5005384003 @default.
• W4280497757 creator A5078663016 @default.
• W4280497757 creator A5079858476 @default.
• W4280497757 creator A5080236384 @default.
• W4280497757 date "2022-07-01" @default.
• W4280497757 modified "2023-10-16" @default.
• W4280497757 title "Surface engineering of Cu catalysts for electrochemical reduction of CO2 to value-added multi-carbon products" @default.
• W4280497757 cites W1971894304 @default.
• W4280497757 cites W1981626052 @default.
• W4280497757 cites W1985178357 @default.
• W4280497757 cites W1991003106 @default.
• W4280497757 cites W1991363019 @default.
• W4280497757 cites W2006046899 @default.
• W4280497757 cites W2026301653 @default.
• W4280497757 cites W2050529292 @default.
• W4280497757 cites W2052417646 @default.
• W4280497757 cites W2066753574 @default.
• W4280497757 cites W2074964984 @default.
• W4280497757 cites W2096300212 @default.
• W4280497757 cites W2137818170 @default.
• W4280497757 cites W2158532118 @default.
• W4280497757 cites W2163494519 @default.
• W4280497757 cites W2170456486 @default.
• W4280497757 cites W2225958871 @default.
• W4280497757 cites W2296901233 @default.
• W4280497757 cites W2317300428 @default.
• W4280497757 cites W2319865050 @default.
• W4280497757 cites W2326170978 @default.
• W4280497757 cites W2336845479 @default.
• W4280497757 cites W2470552650 @default.
• W4280497757 cites W2480341173 @default.
• W4280497757 cites W2483787330 @default.
• W4280497757 cites W2508876682 @default.
• W4280497757 cites W2513116029 @default.
• W4280497757 cites W2515773792 @default.
• W4280497757 cites W2517363922 @default.
• W4280497757 cites W2521614721 @default.
• W4280497757 cites W2528194497 @default.
• W4280497757 cites W2561854106 @default.
• W4280497757 cites W2573313258 @default.
• W4280497757 cites W2582826044 @default.
• W4280497757 cites W2587414341 @default.
• W4280497757 cites W2590930531 @default.
• W4280497757 cites W2608485651 @default.
• W4280497757 cites W2619820429 @default.
• W4280497757 cites W2624335306 @default.
• W4280497757 cites W2625918461 @default.
• W4280497757 cites W2626885970 @default.
• W4280497757 cites W2726732643 @default.
• W4280497757 cites W2746538263 @default.
• W4280497757 cites W2755271205 @default.
• W4280497757 cites W2760460369 @default.
• W4280497757 cites W2783704598 @default.
• W4280497757 cites W2784179142 @default.
• W4280497757 cites W2791036277 @default.
• W4280497757 cites W2795768275 @default.
• W4280497757 cites W2796657374 @default.
• W4280497757 cites W2800329903 @default.
• W4280497757 cites W2803117489 @default.
• W4280497757 cites W2803362190 @default.
• W4280497757 cites W2804235153 @default.
• W4280497757 cites W2805521597 @default.
• W4280497757 cites W2808940939 @default.
• W4280497757 cites W2883336409 @default.
• W4280497757 cites W2887595360 @default.
• W4280497757 cites W2887853995 @default.
• W4280497757 cites W2889577864 @default.
• W4280497757 cites W2890912281 @default.
• W4280497757 cites W2895657821 @default.
• W4280497757 cites W2895982214 @default.
• W4280497757 cites W2896508033 @default.
• W4280497757 cites W2896974626 @default.
• W4280497757 cites W2898639152 @default.
• W4280497757 cites W2900049796 @default.
• W4280497757 cites W2901562382 @default.
• W4280497757 cites W2903280269 @default.
• W4280497757 cites W2908296842 @default.
• W4280497757 cites W2908584685 @default.
• W4280497757 cites W2911112681 @default.
• W4280497757 cites W2911413275 @default.
• W4280497757 cites W2912281710 @default.
• W4280497757 cites W2918265156 @default.
• W4280497757 cites W2924958822 @default.
• W4280497757 cites W2928214500 @default.
• W4280497757 cites W2936627910 @default.
• W4280497757 cites W2937378821 @default.
• W4280497757 cites W2938620684 @default.
• W4280497757 cites W2943498197 @default.
• W4280497757 cites W2947264857 @default.
• W4280497757 cites W2951517373 @default.
• W4280497757 cites W2954268760 @default.
• W4280497757 cites W2964641221 @default.
• W4280497757 cites W2970788487 @default.
• W4280497757 cites W2971019158 @default.
• W4280497757 cites W2971170786 @default.
• W4280497757 cites W2971416524 @default.

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