Matches in SemOpenAlex for { <https://semopenalex.org/work/W4280497956> ?p ?o ?g. }
- W4280497956 abstract "Diazaphospholenes are widely used as hydride transfer catalysts, however their use in radical reactions is a recently emerging area. Here, we show prior stoichiometric radical cyclizations of aryl iodides mediated by diazaphospholene hydrides are made catalytic by the combination of phenylsilane and alkali metal salts to regenerate the diazaphospholene hydride. The scope was expanded to include aryl bromides, which benefit from visible light irradiation. Twenty one substrates underwent cyclization, including a dearomative cyclization. Extension to six intermolecular radical hydroarylations with arenes, thiophenes, and a pyridine was also accomplished." @default.
- W4280497956 created "2022-05-22" @default.
- W4280497956 creator A5003178818 @default.
- W4280497956 creator A5016145924 @default.
- W4280497956 creator A5046157902 @default.
- W4280497956 creator A5071015095 @default.
- W4280497956 date "2022-06-09" @default.
- W4280497956 modified "2023-10-16" @default.
- W4280497956 title "Diazaphospholene‐Catalyzed Radical Reactions from Aryl Halides**" @default.
- W4280497956 cites W1848086109 @default.
- W4280497956 cites W1991646450 @default.
- W4280497956 cites W2053071177 @default.
- W4280497956 cites W2055088909 @default.
- W4280497956 cites W2061659334 @default.
- W4280497956 cites W2065215071 @default.
- W4280497956 cites W2076942509 @default.
- W4280497956 cites W2077359038 @default.
- W4280497956 cites W2079031057 @default.
- W4280497956 cites W2089553882 @default.
- W4280497956 cites W2096411479 @default.
- W4280497956 cites W2119319001 @default.
- W4280497956 cites W2137921601 @default.
- W4280497956 cites W2140364831 @default.
- W4280497956 cites W2148781222 @default.
- W4280497956 cites W2152147124 @default.
- W4280497956 cites W2163854463 @default.
- W4280497956 cites W2171232782 @default.
- W4280497956 cites W2263985178 @default.
- W4280497956 cites W2585035663 @default.
- W4280497956 cites W2610946989 @default.
- W4280497956 cites W2744578848 @default.
- W4280497956 cites W2768027132 @default.
- W4280497956 cites W2781768046 @default.
- W4280497956 cites W2785756486 @default.
- W4280497956 cites W2790899539 @default.
- W4280497956 cites W2811285632 @default.
- W4280497956 cites W2954160932 @default.
- W4280497956 cites W2969449423 @default.
- W4280497956 cites W3010080012 @default.
- W4280497956 cites W3010330000 @default.
- W4280497956 cites W3017595891 @default.
- W4280497956 cites W3022725963 @default.
- W4280497956 cites W3030154064 @default.
- W4280497956 cites W3031217139 @default.
- W4280497956 cites W3039926029 @default.
- W4280497956 cites W3045208108 @default.
- W4280497956 cites W3045633320 @default.
- W4280497956 cites W3083282105 @default.
- W4280497956 cites W3090006914 @default.
- W4280497956 cites W3162353279 @default.
- W4280497956 cites W3189989431 @default.
- W4280497956 cites W4200155990 @default.
- W4280497956 cites W4225548005 @default.
- W4280497956 cites W4233444316 @default.
- W4280497956 cites W4233633554 @default.
- W4280497956 cites W4234787622 @default.
- W4280497956 cites W4241291144 @default.
- W4280497956 cites W4241658855 @default.
- W4280497956 cites W4244172651 @default.
- W4280497956 cites W4253959847 @default.
- W4280497956 doi "https://doi.org/10.1002/anie.202204088" @default.
- W4280497956 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35583316" @default.
- W4280497956 hasPublicationYear "2022" @default.
- W4280497956 type Work @default.
- W4280497956 citedByCount "5" @default.
- W4280497956 countsByYear W42804979562022 @default.
- W4280497956 countsByYear W42804979562023 @default.
- W4280497956 crossrefType "journal-article" @default.
- W4280497956 hasAuthorship W4280497956A5003178818 @default.
- W4280497956 hasAuthorship W4280497956A5016145924 @default.
- W4280497956 hasAuthorship W4280497956A5046157902 @default.
- W4280497956 hasAuthorship W4280497956A5071015095 @default.
- W4280497956 hasConcept C139066938 @default.
- W4280497956 hasConcept C161790260 @default.
- W4280497956 hasConcept C171560689 @default.
- W4280497956 hasConcept C178790620 @default.
- W4280497956 hasConcept C185592680 @default.
- W4280497956 hasConcept C2777079010 @default.
- W4280497956 hasConcept C2777389692 @default.
- W4280497956 hasConcept C2777961443 @default.
- W4280497956 hasConcept C2780263894 @default.
- W4280497956 hasConcept C2781076698 @default.
- W4280497956 hasConcept C45849291 @default.
- W4280497956 hasConcept C544153396 @default.
- W4280497956 hasConcept C65165184 @default.
- W4280497956 hasConcept C75473681 @default.
- W4280497956 hasConceptScore W4280497956C139066938 @default.
- W4280497956 hasConceptScore W4280497956C161790260 @default.
- W4280497956 hasConceptScore W4280497956C171560689 @default.
- W4280497956 hasConceptScore W4280497956C178790620 @default.
- W4280497956 hasConceptScore W4280497956C185592680 @default.
- W4280497956 hasConceptScore W4280497956C2777079010 @default.
- W4280497956 hasConceptScore W4280497956C2777389692 @default.
- W4280497956 hasConceptScore W4280497956C2777961443 @default.
- W4280497956 hasConceptScore W4280497956C2780263894 @default.
- W4280497956 hasConceptScore W4280497956C2781076698 @default.
- W4280497956 hasConceptScore W4280497956C45849291 @default.
- W4280497956 hasConceptScore W4280497956C544153396 @default.
- W4280497956 hasConceptScore W4280497956C65165184 @default.
- W4280497956 hasConceptScore W4280497956C75473681 @default.