Matches in SemOpenAlex for { <https://semopenalex.org/work/W4280501666> ?p ?o ?g. }
- W4280501666 endingPage "121531" @default.
- W4280501666 startingPage "121531" @default.
- W4280501666 abstract "Electrochemical nitrogen reduction reaction can be adopted to generate renewable ammonia. That is recognized as a sustainable alternative to the Haber-Bosch process. However, the limited electrocatalytic activity remains the primary obstacle against viable application of the electrocatalytic ammonia fixation. Herein, a biomimetic three-dimensional NiCoP/CoMoP/Co(Mo 3 Se 4 ) 4 @C/NF electrocatalyst is designed to have excellent NRR performance with an NH 3 yield rate of 24.54 μg h −1 cm −2 and Faradaic efficiency of 23.15%. Based on the experimental and theoretical results, NiCoP/CoMoP/Co(Mo 3 Se 4 ) 4 @C/NF electrocatalyst perfectly simulates the structural characteristics of biological nitrogenase, where Co(Mo 3 Se 4 ) 4 acts as the major active center while NiCoP and CoMoP contribute to controlling the electron transfer during NRR. Additionally, the coexistence of the three different heterojunction interfaces induces more effective electronic structure modulation compared with the single interface, thereby optimizing the reaction energy barrier of intermediates. This work has developed a synergistic strategy to boost the reaction kinetics via introducing multiple heterojunction interfaces. • NiCoP/CoMoP/Co(Mo 3 Se 4 ) 4 @C/NF have excellent N 2 reduction performance. • NiCoP/CoMoP/Co(Mo 3 Se 4 ) 4 @C/NF simulates the structure of nitrogenase. • Multiple heterojunction interfaces induce effective electron redistribution. • Multiple heterojunction interfaces optimize the reaction energy barrier." @default.
- W4280501666 created "2022-05-22" @default.
- W4280501666 creator A5003003776 @default.
- W4280501666 creator A5006250732 @default.
- W4280501666 creator A5014539863 @default.
- W4280501666 creator A5022526821 @default.
- W4280501666 creator A5059197509 @default.
- W4280501666 creator A5067368667 @default.
- W4280501666 creator A5073779528 @default.
- W4280501666 creator A5086602956 @default.
- W4280501666 date "2022-10-01" @default.
- W4280501666 modified "2023-10-18" @default.
- W4280501666 title "Bio-inspired NiCoP/CoMoP/Co(Mo3Se4)4 @C/NF multi-heterojunction nanoflowers：Effective catalytic nitrogen reduction by driving electron transfer" @default.
- W4280501666 cites W1940696028 @default.
- W4280501666 cites W2038851518 @default.
- W4280501666 cites W2084077391 @default.
- W4280501666 cites W2087890306 @default.
- W4280501666 cites W2092157292 @default.
- W4280501666 cites W2556334122 @default.
- W4280501666 cites W2591686856 @default.
- W4280501666 cites W2784257035 @default.
- W4280501666 cites W2792027158 @default.
- W4280501666 cites W2803438242 @default.
- W4280501666 cites W2809806541 @default.
- W4280501666 cites W2893142138 @default.
- W4280501666 cites W2900400642 @default.
- W4280501666 cites W2910483443 @default.
- W4280501666 cites W2913399789 @default.
- W4280501666 cites W2914089611 @default.
- W4280501666 cites W2914840694 @default.
- W4280501666 cites W2918930942 @default.
- W4280501666 cites W2920912088 @default.
- W4280501666 cites W2946174900 @default.
- W4280501666 cites W2946199134 @default.
- W4280501666 cites W2946633992 @default.
- W4280501666 cites W2963024852 @default.
- W4280501666 cites W2969932786 @default.
- W4280501666 cites W2974623595 @default.
- W4280501666 cites W2974866817 @default.
- W4280501666 cites W2977048693 @default.
- W4280501666 cites W2996859290 @default.
- W4280501666 cites W2999584513 @default.
- W4280501666 cites W3002561092 @default.
- W4280501666 cites W3007099140 @default.
- W4280501666 cites W3018229495 @default.
- W4280501666 cites W3020198492 @default.
- W4280501666 cites W3021563181 @default.
- W4280501666 cites W3023252604 @default.
- W4280501666 cites W3029551610 @default.
- W4280501666 cites W3030589897 @default.
- W4280501666 cites W3035190513 @default.
- W4280501666 cites W3038217570 @default.
- W4280501666 cites W3094431402 @default.
- W4280501666 cites W3107369030 @default.
- W4280501666 cites W3112668193 @default.
- W4280501666 cites W3126217714 @default.
- W4280501666 cites W3128965051 @default.
- W4280501666 cites W3131697798 @default.
- W4280501666 cites W3132637230 @default.
- W4280501666 cites W3156497808 @default.
- W4280501666 cites W3159383200 @default.
- W4280501666 cites W3159551265 @default.
- W4280501666 cites W3168309679 @default.
- W4280501666 cites W3177854026 @default.
- W4280501666 cites W3192712834 @default.
- W4280501666 cites W4200042981 @default.
- W4280501666 cites W4213051491 @default.
- W4280501666 cites W4214704737 @default.
- W4280501666 doi "https://doi.org/10.1016/j.apcatb.2022.121531" @default.
- W4280501666 hasPublicationYear "2022" @default.
- W4280501666 type Work @default.
- W4280501666 citedByCount "18" @default.
- W4280501666 countsByYear W42805016662022 @default.
- W4280501666 countsByYear W42805016662023 @default.
- W4280501666 crossrefType "journal-article" @default.
- W4280501666 hasAuthorship W4280501666A5003003776 @default.
- W4280501666 hasAuthorship W4280501666A5006250732 @default.
- W4280501666 hasAuthorship W4280501666A5014539863 @default.
- W4280501666 hasAuthorship W4280501666A5022526821 @default.
- W4280501666 hasAuthorship W4280501666A5059197509 @default.
- W4280501666 hasAuthorship W4280501666A5067368667 @default.
- W4280501666 hasAuthorship W4280501666A5073779528 @default.
- W4280501666 hasAuthorship W4280501666A5086602956 @default.
- W4280501666 hasConcept C111335779 @default.
- W4280501666 hasConcept C123669783 @default.
- W4280501666 hasConcept C127413603 @default.
- W4280501666 hasConcept C161790260 @default.
- W4280501666 hasConcept C171250308 @default.
- W4280501666 hasConcept C178790620 @default.
- W4280501666 hasConcept C185592680 @default.
- W4280501666 hasConcept C192562407 @default.
- W4280501666 hasConcept C2524010 @default.
- W4280501666 hasConcept C33923547 @default.
- W4280501666 hasConcept C42360764 @default.
- W4280501666 hasConcept C49040817 @default.
- W4280501666 hasConcept C537208039 @default.
- W4280501666 hasConcept C55493867 @default.
- W4280501666 hasConcept C75473681 @default.