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• W4280530759 abstract "Abstract Conventional methods for the general and efficient synthesis of 4‐hydroxybenzo‐ phenones are extremely underdeveloped and limited. We herein report a challenging metal‐free protocol to rapidly construct 4‐hydroxybenzophenones from para ‐quinone methides ( p ‐QMs) in DMSO in the presence of KOH using the inexpensive and readily available elemental sulfur as redox reagent. As an unprecedented method, this simple but efficient approach has excellent site specificity, green sustainability, excellent atomic economy, and broad functional group compatibilities. Mechanistic studies show that the novel reaction proceeds through a radical pathway." @default.
• W4280530759 created "2022-05-22" @default.
• W4280530759 creator A5005960467 @default.
• W4280530759 creator A5013417698 @default.
• W4280530759 creator A5037437942 @default.
• W4280530759 creator A5037458498 @default.
• W4280530759 creator A5044926048 @default.
• W4280530759 creator A5047022017 @default.
• W4280530759 creator A5081673829 @default.
• W4280530759 creator A5090114526 @default.
• W4280530759 date "2022-05-12" @default.
• W4280530759 modified "2023-10-16" @default.
• W4280530759 title "Elemental Sulfur‐Promoted Synthesis of 4‐Hydroxybenzophenones from <i>p</i>‐Quinone Methides under Metal‐Free Condition" @default.
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