Matches in SemOpenAlex for { <https://semopenalex.org/work/W4280536053> ?p ?o ?g. }
- W4280536053 abstract "Abstract The BP unsaturated unit is a very attractive functional group as it provides novel reactivity and unique physical properties. Nonetheless, applications remain limited so far due to the bulky nature of B/P‐protecting groups, required to prevent oligomerization. Herein, we report the synthesis and isolation of a N ‐heterocyclic carbene (NHC)‐stabilized phosphaborene, bearing a trimethylsilyl (TMS) functionality at the P‐terminal, as a room‐temperature‐stable crystalline solid accessible via facile NHC‐induced trimethylsilyl chloride (TMSCl) elimination from its phosphinoborane precursor. This phosphaborene compound, bearing a genuine B=P bond, exhibits a remarkable ability for undergoing P‐centre metathesis reactions, which allows the isolation of a series of unprecedented phosphaborenes. X‐ray crystallographic analysis, UV/Vis spectroscopy, and DFT calculations provide insights into the B=P bonding situation." @default.
- W4280536053 created "2022-05-22" @default.
- W4280536053 creator A5038207247 @default.
- W4280536053 creator A5039534982 @default.
- W4280536053 creator A5057775238 @default.
- W4280536053 date "2022-06-23" @default.
- W4280536053 modified "2023-10-09" @default.
- W4280536053 title "Metathesis Reactions of a NHC‐Stabilized Phosphaborene" @default.
- W4280536053 cites W1482232064 @default.
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- W4280536053 cites W1963675663 @default.
- W4280536053 cites W1964038229 @default.
- W4280536053 cites W1969514980 @default.
- W4280536053 cites W1970401420 @default.
- W4280536053 cites W1971428915 @default.
- W4280536053 cites W1973438031 @default.
- W4280536053 cites W1979125213 @default.
- W4280536053 cites W1982539668 @default.
- W4280536053 cites W1993104459 @default.
- W4280536053 cites W1993933718 @default.
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- W4280536053 cites W2000024623 @default.
- W4280536053 cites W2000875788 @default.
- W4280536053 cites W2003006920 @default.
- W4280536053 cites W2012584132 @default.
- W4280536053 cites W2014337476 @default.
- W4280536053 cites W2018399908 @default.
- W4280536053 cites W2021416828 @default.
- W4280536053 cites W2025961773 @default.
- W4280536053 cites W2029168981 @default.
- W4280536053 cites W2033231873 @default.
- W4280536053 cites W2040726183 @default.
- W4280536053 cites W2044571535 @default.
- W4280536053 cites W2046035292 @default.
- W4280536053 cites W2056805179 @default.
- W4280536053 cites W2063851575 @default.
- W4280536053 cites W2069329659 @default.
- W4280536053 cites W2077686706 @default.
- W4280536053 cites W2082692212 @default.
- W4280536053 cites W2092307593 @default.
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- W4280536053 cites W2144452705 @default.
- W4280536053 cites W2144821086 @default.
- W4280536053 cites W2148517659 @default.
- W4280536053 cites W2151327267 @default.
- W4280536053 cites W2152537528 @default.
- W4280536053 cites W2156577760 @default.
- W4280536053 cites W2157698930 @default.
- W4280536053 cites W2160790360 @default.
- W4280536053 cites W2162580580 @default.
- W4280536053 cites W2162798782 @default.
- W4280536053 cites W2165253538 @default.
- W4280536053 cites W2170676330 @default.
- W4280536053 cites W2274738732 @default.
- W4280536053 cites W2319796813 @default.
- W4280536053 cites W2320739946 @default.
- W4280536053 cites W2335170026 @default.
- W4280536053 cites W2540261990 @default.
- W4280536053 cites W2577787397 @default.
- W4280536053 cites W2744091949 @default.
- W4280536053 cites W2748066185 @default.
- W4280536053 cites W2783161192 @default.
- W4280536053 cites W2789134065 @default.
- W4280536053 cites W2884012718 @default.
- W4280536053 cites W2887496544 @default.
- W4280536053 cites W2939144999 @default.
- W4280536053 cites W2953051109 @default.
- W4280536053 cites W2953559513 @default.
- W4280536053 cites W2988270617 @default.
- W4280536053 cites W2999532798 @default.
- W4280536053 cites W3007443364 @default.
- W4280536053 cites W3045842505 @default.
- W4280536053 cites W3090859933 @default.
- W4280536053 cites W3096627345 @default.
- W4280536053 cites W3165769897 @default.
- W4280536053 cites W3166449452 @default.
- W4280536053 cites W3189984370 @default.
- W4280536053 cites W3195774576 @default.
- W4280536053 cites W3205912616 @default.
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- W4280536053 cites W4230255045 @default.
- W4280536053 cites W4255656412 @default.
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- W4280536053 doi "https://doi.org/10.1002/anie.202203345" @default.
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- W4280536053 hasPublicationYear "2022" @default.
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