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- W4280543702 abstract "The luminescence properties of NaMgF3:Sm and NaMgF3:Ce,Sm were studied in the vacuum ultraviolet spectral region. Excitation bands corresponding to the charge transfer processes F- → Sm3+, O2- → Sm3+, and O2- → Ce3+, and the energy transfer processes Ce3+ → Sm3+and O2- → Sm3+, were observed. The energies of the Sm3+charge transfer transitions and the crystal field split Ce3+4f05d1transitions were used to construct a complete host referred binding energy diagram for the series of lanthanide-doped NaMgF3:Ln compounds. We demonstrate that the optical and luminescence properties predicted by the binding energy diagram are in good agreement with those predicted by the binding energy diagram constructed via the alternative impurity-informed method, and all available experimental data regarding the NaMgF3:Ln compounds. We demonstrate that NaMgF3:Ln compounds are model systems for the study of charge trapping phenomena and divalent lanthanide luminescence. Ultimately, we validate that the impurity-informed method can be used to establish the energy levels of lanthanides in fluoride systems." @default.
- W4280543702 created "2022-05-22" @default.
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- W4280543702 date "2022-05-25" @default.
- W4280543702 modified "2023-10-02" @default.
- W4280543702 title "Vacuum ultraviolet photoluminescence of NaMgF<sub>3</sub>:Sm and NaMgF<sub>3</sub>:Sm,Ce: energy levels of the lanthanides in NaMgF<sub>3</sub>:Ln compounds" @default.
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- W4280543702 doi "https://doi.org/10.1088/2050-6120/ac70aa" @default.
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