Matches in SemOpenAlex for { <https://semopenalex.org/work/W4280561625> ?p ?o ?g. }
- W4280561625 endingPage "134971" @default.
- W4280561625 startingPage "134971" @default.
- W4280561625 abstract "Red phosphorus (P) is one of the metalloid materials, with five external electrons, it should be an excellent electron donor. However, the activity of red P to reduce Cr6+ is limited. Due to electrostatic repulsion, it is difficult for the electrons on the red P to transfer to the chromate anion (Cr6+). Interestingly, we found that Fe3+ derived from rust, waste iron or Fe3+ reagents can be used as the electron transport medium to solve the electron transport obstacles between red P and Cr6+. As a result, the reduction of Cr6+ by red P/rust system takes only 20 min, which is far lower than the 140 min of red P. The reduction rate of Cr6+ in the red P/rust system is about 12.3 times that of red P. The reaction mechanism is that red P is not easy to access chromate anions but can easily adsorb Fe3+. The adsorbed Fe3+ will be reduced to Fe2+ by red P, and the regenerated Fe2+ will diffuse into the solution to rapidly reduce Cr6+. Therefore, this work provides an alternative waste iron reuse pathway and also sheds light on the important role of electron medium in reduction reaction." @default.
- W4280561625 created "2022-05-22" @default.
- W4280561625 creator A5015438671 @default.
- W4280561625 creator A5015568917 @default.
- W4280561625 creator A5035018880 @default.
- W4280561625 creator A5039860928 @default.
- W4280561625 creator A5063261566 @default.
- W4280561625 creator A5086231149 @default.
- W4280561625 creator A5087356906 @default.
- W4280561625 date "2022-09-01" @default.
- W4280561625 modified "2023-09-27" @default.
- W4280561625 title "Rust triggers rapid reduction of Cr6+ by red phosphorus: The importance of electronic transfer medium of Fe3+" @default.
- W4280561625 cites W1627657003 @default.
- W4280561625 cites W1965376404 @default.
- W4280561625 cites W1993054776 @default.
- W4280561625 cites W2003076570 @default.
- W4280561625 cites W2015982771 @default.
- W4280561625 cites W2042883196 @default.
- W4280561625 cites W2049153042 @default.
- W4280561625 cites W2056533695 @default.
- W4280561625 cites W2065387926 @default.
- W4280561625 cites W2068584903 @default.
- W4280561625 cites W2098133115 @default.
- W4280561625 cites W2347178261 @default.
- W4280561625 cites W2415363010 @default.
- W4280561625 cites W2559781199 @default.
- W4280561625 cites W2586903497 @default.
- W4280561625 cites W2591681883 @default.
- W4280561625 cites W2601604520 @default.
- W4280561625 cites W2735671670 @default.
- W4280561625 cites W2748921036 @default.
- W4280561625 cites W2795328139 @default.
- W4280561625 cites W2796045986 @default.
- W4280561625 cites W2891022562 @default.
- W4280561625 cites W2900014651 @default.
- W4280561625 cites W2904600940 @default.
- W4280561625 cites W2914389200 @default.
- W4280561625 cites W2920668497 @default.
- W4280561625 cites W2927052818 @default.
- W4280561625 cites W2969308506 @default.
- W4280561625 cites W2983155209 @default.
- W4280561625 cites W2991918014 @default.
- W4280561625 cites W2996435682 @default.
- W4280561625 cites W3000754753 @default.
- W4280561625 cites W3016808622 @default.
- W4280561625 cites W3019879628 @default.
- W4280561625 cites W3022618098 @default.
- W4280561625 cites W3023181027 @default.
- W4280561625 cites W3030047948 @default.
- W4280561625 cites W3039403738 @default.
- W4280561625 cites W3041915824 @default.
- W4280561625 cites W3047306106 @default.
- W4280561625 cites W3089762001 @default.
- W4280561625 cites W3093303391 @default.
- W4280561625 cites W3095812129 @default.
- W4280561625 cites W3106460030 @default.
- W4280561625 cites W3119352395 @default.
- W4280561625 cites W3126086557 @default.
- W4280561625 cites W3148043058 @default.
- W4280561625 cites W3164222511 @default.
- W4280561625 cites W3183087583 @default.
- W4280561625 cites W65938566 @default.
- W4280561625 doi "https://doi.org/10.1016/j.chemosphere.2022.134971" @default.
- W4280561625 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35588886" @default.
- W4280561625 hasPublicationYear "2022" @default.
- W4280561625 type Work @default.
- W4280561625 citedByCount "3" @default.
- W4280561625 countsByYear W42805616252022 @default.
- W4280561625 countsByYear W42805616252023 @default.
- W4280561625 crossrefType "journal-article" @default.
- W4280561625 hasAuthorship W4280561625A5015438671 @default.
- W4280561625 hasAuthorship W4280561625A5015568917 @default.
- W4280561625 hasAuthorship W4280561625A5035018880 @default.
- W4280561625 hasAuthorship W4280561625A5039860928 @default.
- W4280561625 hasAuthorship W4280561625A5063261566 @default.
- W4280561625 hasAuthorship W4280561625A5086231149 @default.
- W4280561625 hasAuthorship W4280561625A5087356906 @default.
- W4280561625 hasConcept C121332964 @default.
- W4280561625 hasConcept C123669783 @default.
- W4280561625 hasConcept C145148216 @default.
- W4280561625 hasConcept C147120987 @default.
- W4280561625 hasConcept C147789679 @default.
- W4280561625 hasConcept C150394285 @default.
- W4280561625 hasConcept C178790620 @default.
- W4280561625 hasConcept C179104552 @default.
- W4280561625 hasConcept C185592680 @default.
- W4280561625 hasConcept C197781089 @default.
- W4280561625 hasConcept C199360897 @default.
- W4280561625 hasConcept C205688572 @default.
- W4280561625 hasConcept C24840226 @default.
- W4280561625 hasConcept C40875361 @default.
- W4280561625 hasConcept C41008148 @default.
- W4280561625 hasConcept C511782168 @default.
- W4280561625 hasConcept C55493867 @default.
- W4280561625 hasConcept C62520636 @default.
- W4280561625 hasConcept C75473681 @default.
- W4280561625 hasConceptScore W4280561625C121332964 @default.
- W4280561625 hasConceptScore W4280561625C123669783 @default.