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- W4280565751 abstract "The lifetime of lithium-ion batteries can be extended by applying protective coatings to the cathode's surface. Many studies explore atomic layer deposition (ALD) for this purpose. However, the complementary molecular layer deposition (MLD) technique might offer the benefit of depositing hybrid coatings that are flexible and can accommodate potential volume changes of the electrode during charging and discharging of the battery. This study reports the deposition of titanium carboxylate thin films via MLD. The structure and stability of the hybrid films are studied by using Fourier transform IR spectroscopy. The electrochemical properties of two titanium carboxylate films and a titanicone MLD film, deposited by using TDMAT and glycerol, are evaluated on top of a TiO2, TiN, and LiMn2O4 electrode. The coatings are found to present good lithium-ion kinetics and to reduce electrolyte decomposition. Overall, the titanium carboxylate films deposited in this work seem promising as protective and elastic coatings for future high-energy lithium-ion battery cathodes." @default.
- W4280565751 created "2022-05-22" @default.
- W4280565751 creator A5001597412 @default.
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- W4280565751 date "2022-05-20" @default.
- W4280565751 modified "2023-10-16" @default.
- W4280565751 title "Titanium Carboxylate Molecular Layer Deposited Hybrid Films as Protective Coatings for Lithium-Ion Batteries" @default.
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- W4280565751 doi "https://doi.org/10.1021/acsami.2c03511" @default.
- W4280565751 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35590474" @default.
- W4280565751 hasPublicationYear "2022" @default.
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