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- W4280584927 abstract "Two-dimensional ferroelectrics with moderate band gap enable unprecedented applications in optoelectronics. Here, we report that the photogalvanic effect (PGE) of narrow-band-gap semiconductor bilayer ZrI2 is significantly enhanced by the interlayer sliding which turns out to be ferroelectric with both in-plane and out-of-plane polarizations. The intrinsic ferroelectric field promotes the separation efficiency of photogenerated carriers and reduces the recombination rate of electron–hole pairs, thus improving the photoelectric conversion efficiency and resulting in a larger photoresponse. The magnitude of the maximum photoresponse in the bilayer β-ZrI2 (ferroelectric) is enhanced by about 5 times than in the bilayer s-ZrI2 (paraelectric). A robust broadband photoresponse from mid-infrared to visible can be found from its photodetector. Our results provide great insights to engineering novel optoelectronic applications by ferroelectric slidetronics." @default.
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- W4280584927 date "2022-08-01" @default.
- W4280584927 modified "2023-10-04" @default.
- W4280584927 title "Enhanced photogalvanic effect in a 2D ferroelectric ZrI2 by interlayer sliding" @default.
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- W4280584927 doi "https://doi.org/10.1016/j.physe.2022.115297" @default.
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