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• W4280603467 endingPage "8570" @default.
• W4280603467 startingPage "8557" @default.
• W4280603467 abstract "Understanding how a ligand affects the steric and electronic properties of a metal is the cornerstone of the inorganic chemistry enterprise. What happens when the ligand is an extended surface? This question is central to the design and implementation of state-of-the-art functional materials containing transition metals. This perspective will describe how these two very different sets of extended surfaces can form well-defined coordination complexes with metals. In the Green formalism, functionalities on oxide surfaces react with inorganics to form species that contain X-type or LX-type interactions between the metal and the oxide. Carbon surfaces are neutral L-type ligands; this perspective focuses on carbons that donate six electrons to a metal. The nature of this interaction depends on the curvature, and thereby orbital overlap, between the metal and the extended π-system from the nanocarbon." @default.
• W4280603467 created "2022-05-22" @default.
• W4280603467 creator A5007301482 @default.
• W4280603467 creator A5034750516 @default.
• W4280603467 date "2022-01-01" @default.
• W4280603467 modified "2023-10-18" @default.
• W4280603467 title "The coordination chemistry of oxide and nanocarbon materials" @default.
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