Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281256431> ?p ?o ?g. }
- W4281256431 endingPage "121527" @default.
- W4281256431 startingPage "121527" @default.
- W4281256431 abstract "Here, we provide an in-depth understanding of the catalytic mechanism of sodium for the carburization of α-Fe catalyst by C2H4 in contrast to traditional CO through an approach combing in situ XRD and molecular orbital theory, considering the carburization of iron-based catalyst to active iron carbides is a prerequisite step to display activity in CO/CO2 hydrogenation. In situ XRD experiments show that sodium can trigger the carburization of α-Fe by CO and accelerate the accumulation of carbon-rich iron carbides, due to the enhanced electron back-donation from d band in Fe surface to 2π* orbitals in CO, thereby facilitating the dissociation of CO and the carburization by CO. Nevertheless, sodium shows a contrary effect on the carburization of α-Fe under C2H4, due to the significant increase of the total dissociative energy, thereby facilitating the desorption instead of dissociation of C2H4 on Fe surface, finally inhibiting the carburization." @default.
- W4281256431 created "2022-05-23" @default.
- W4281256431 creator A5000251609 @default.
- W4281256431 creator A5038745250 @default.
- W4281256431 creator A5042377211 @default.
- W4281256431 creator A5047313833 @default.
- W4281256431 creator A5052242927 @default.
- W4281256431 creator A5069927107 @default.
- W4281256431 creator A5075059527 @default.
- W4281256431 date "2022-10-01" @default.
- W4281256431 modified "2023-10-13" @default.
- W4281256431 title "Elucidating the effect of sodium on the carburization behaviors of α-Fe under CO or C2H4" @default.
- W4281256431 cites W1967796261 @default.
- W4281256431 cites W1970127494 @default.
- W4281256431 cites W1981368803 @default.
- W4281256431 cites W1984405429 @default.
- W4281256431 cites W1987805085 @default.
- W4281256431 cites W1997845317 @default.
- W4281256431 cites W1998258943 @default.
- W4281256431 cites W2007395042 @default.
- W4281256431 cites W2013162029 @default.
- W4281256431 cites W2029561879 @default.
- W4281256431 cites W2034169695 @default.
- W4281256431 cites W2036113194 @default.
- W4281256431 cites W2036412392 @default.
- W4281256431 cites W2036625944 @default.
- W4281256431 cites W2053969011 @default.
- W4281256431 cites W2054900848 @default.
- W4281256431 cites W2063153486 @default.
- W4281256431 cites W2064877675 @default.
- W4281256431 cites W2071694041 @default.
- W4281256431 cites W2073065588 @default.
- W4281256431 cites W2088694456 @default.
- W4281256431 cites W2128389493 @default.
- W4281256431 cites W2333898688 @default.
- W4281256431 cites W2340612282 @default.
- W4281256431 cites W237098726 @default.
- W4281256431 cites W2477980016 @default.
- W4281256431 cites W2559613417 @default.
- W4281256431 cites W2577199741 @default.
- W4281256431 cites W2626360167 @default.
- W4281256431 cites W2754621891 @default.
- W4281256431 cites W2794259011 @default.
- W4281256431 cites W2810641607 @default.
- W4281256431 cites W2891598251 @default.
- W4281256431 cites W2900935959 @default.
- W4281256431 cites W2904588570 @default.
- W4281256431 cites W2917725526 @default.
- W4281256431 cites W2946700511 @default.
- W4281256431 cites W3053686616 @default.
- W4281256431 cites W3080833183 @default.
- W4281256431 cites W3101339603 @default.
- W4281256431 cites W3128599808 @default.
- W4281256431 cites W3133893415 @default.
- W4281256431 cites W3140116825 @default.
- W4281256431 cites W3164576411 @default.
- W4281256431 cites W3183973745 @default.
- W4281256431 cites W3204152707 @default.
- W4281256431 cites W3208692786 @default.
- W4281256431 cites W4210291387 @default.
- W4281256431 cites W4210416838 @default.
- W4281256431 doi "https://doi.org/10.1016/j.apcatb.2022.121527" @default.
- W4281256431 hasPublicationYear "2022" @default.
- W4281256431 type Work @default.
- W4281256431 citedByCount "3" @default.
- W4281256431 countsByYear W42812564312023 @default.
- W4281256431 crossrefType "journal-article" @default.
- W4281256431 hasAuthorship W4281256431A5000251609 @default.
- W4281256431 hasAuthorship W4281256431A5038745250 @default.
- W4281256431 hasAuthorship W4281256431A5042377211 @default.
- W4281256431 hasAuthorship W4281256431A5047313833 @default.
- W4281256431 hasAuthorship W4281256431A5052242927 @default.
- W4281256431 hasAuthorship W4281256431A5069927107 @default.
- W4281256431 hasAuthorship W4281256431A5075059527 @default.
- W4281256431 hasConcept C102931765 @default.
- W4281256431 hasConcept C127413603 @default.
- W4281256431 hasConcept C147789679 @default.
- W4281256431 hasConcept C150394285 @default.
- W4281256431 hasConcept C161790260 @default.
- W4281256431 hasConcept C162711632 @default.
- W4281256431 hasConcept C179104552 @default.
- W4281256431 hasConcept C185592680 @default.
- W4281256431 hasConcept C191897082 @default.
- W4281256431 hasConcept C192562407 @default.
- W4281256431 hasConcept C42360764 @default.
- W4281256431 hasConcept C5335593 @default.
- W4281256431 hasConcept C537181965 @default.
- W4281256431 hasConcept C55493867 @default.
- W4281256431 hasConceptScore W4281256431C102931765 @default.
- W4281256431 hasConceptScore W4281256431C127413603 @default.
- W4281256431 hasConceptScore W4281256431C147789679 @default.
- W4281256431 hasConceptScore W4281256431C150394285 @default.
- W4281256431 hasConceptScore W4281256431C161790260 @default.
- W4281256431 hasConceptScore W4281256431C162711632 @default.
- W4281256431 hasConceptScore W4281256431C179104552 @default.
- W4281256431 hasConceptScore W4281256431C185592680 @default.
- W4281256431 hasConceptScore W4281256431C191897082 @default.
- W4281256431 hasConceptScore W4281256431C192562407 @default.