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- W4281285383 abstract "Due to high ring strain energies, cyclopropanols and cyclobutanols have a strong tendency of breaking the endocyclic C–C bonds to participate in versatile organic transformations. With an inherent three-dimensional structure, cyclopropanols and cyclobutanols have the advantage of synthesizing linear or cyclic molecules with stereogenic centers via ring-opening asymmetric synthesis. There are three strategies for the ring-opening of cyclopropanols and cyclobutanols usually involved in asymmetric synthesis: 1) β-carbon elimination of metal alkoxide; 2) radical ring-opening; 3) ring-opening via semipinacol rearrangement. The present review has highlighted the progress developed in the last five years." @default.
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- W4281285383 date "2022-08-01" @default.
- W4281285383 modified "2023-10-16" @default.
- W4281285383 title "Recent advances using cyclopropanols and cyclobutanols in ring-opening asymmetric synthesis" @default.
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- W4281285383 doi "https://doi.org/10.1016/j.gresc.2022.05.007" @default.
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