Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281288714> ?p ?o ?g. }
- W4281288714 endingPage "7530" @default.
- W4281288714 startingPage "7521" @default.
- W4281288714 abstract "A ruthenium-catalyzed asymmetric transfer hydrogenation of 2,3-disubstituted flavanones was developed for the construction of three contiguous stereocenters under basic conditions through a combination of dynamic kinetic resolution and retro-oxa-Michael addition, giving chiral flavanols with excellent enantioselectivities and diastereoselectivities. The reaction proceeded via a base-catalyzed retro-oxa-Michael addition to racemize two stereogenic centers simultaneously in concert with a highly enantioselective ketone transfer hydrogenation step. The asymmetric transfer hydrogenation could be achieved at gram scale without loss of the activity and enantioselectivity." @default.
- W4281288714 created "2022-05-24" @default.
- W4281288714 creator A5018596226 @default.
- W4281288714 creator A5048355915 @default.
- W4281288714 creator A5073407872 @default.
- W4281288714 creator A5075511300 @default.
- W4281288714 creator A5087382230 @default.
- W4281288714 date "2022-05-23" @default.
- W4281288714 modified "2023-10-15" @default.
- W4281288714 title "Asymmetric Transfer Hydrogenation of 2,3-Disubstituted Flavanones through Dynamic Kinetic Resolution Enabled by Retro-Oxa-Michael Addition: Construction of Three Contiguous Stereogenic Centers" @default.
- W4281288714 cites W1858744052 @default.
- W4281288714 cites W1946387153 @default.
- W4281288714 cites W1964060855 @default.
- W4281288714 cites W1967885370 @default.
- W4281288714 cites W1971211899 @default.
- W4281288714 cites W1978717953 @default.
- W4281288714 cites W1981328271 @default.
- W4281288714 cites W1982316743 @default.
- W4281288714 cites W1983586859 @default.
- W4281288714 cites W1996224377 @default.
- W4281288714 cites W2009884940 @default.
- W4281288714 cites W2012028316 @default.
- W4281288714 cites W2013160605 @default.
- W4281288714 cites W2013434549 @default.
- W4281288714 cites W2015937918 @default.
- W4281288714 cites W2041715257 @default.
- W4281288714 cites W2047555987 @default.
- W4281288714 cites W2068883492 @default.
- W4281288714 cites W2071562105 @default.
- W4281288714 cites W2076755318 @default.
- W4281288714 cites W2088967061 @default.
- W4281288714 cites W2097446202 @default.
- W4281288714 cites W2099045600 @default.
- W4281288714 cites W2102178957 @default.
- W4281288714 cites W2111184875 @default.
- W4281288714 cites W2121801825 @default.
- W4281288714 cites W2127721564 @default.
- W4281288714 cites W2147241419 @default.
- W4281288714 cites W2157485175 @default.
- W4281288714 cites W2222089755 @default.
- W4281288714 cites W2289236981 @default.
- W4281288714 cites W2292975024 @default.
- W4281288714 cites W2306317410 @default.
- W4281288714 cites W2309842391 @default.
- W4281288714 cites W2317490527 @default.
- W4281288714 cites W2332799615 @default.
- W4281288714 cites W2338756977 @default.
- W4281288714 cites W2340082778 @default.
- W4281288714 cites W2465709002 @default.
- W4281288714 cites W2516528742 @default.
- W4281288714 cites W2522268935 @default.
- W4281288714 cites W2569673403 @default.
- W4281288714 cites W2613920727 @default.
- W4281288714 cites W2751943562 @default.
- W4281288714 cites W2788685868 @default.
- W4281288714 cites W2799404707 @default.
- W4281288714 cites W2886242041 @default.
- W4281288714 cites W2891106043 @default.
- W4281288714 cites W2901041012 @default.
- W4281288714 cites W2901544895 @default.
- W4281288714 cites W2950603306 @default.
- W4281288714 cites W2951770928 @default.
- W4281288714 cites W2952629994 @default.
- W4281288714 cites W2972469720 @default.
- W4281288714 cites W2977639927 @default.
- W4281288714 cites W2985406166 @default.
- W4281288714 cites W2995496309 @default.
- W4281288714 cites W3044583701 @default.
- W4281288714 cites W3082582706 @default.
- W4281288714 cites W3084280981 @default.
- W4281288714 cites W3087459086 @default.
- W4281288714 cites W3092065598 @default.
- W4281288714 cites W3115287964 @default.
- W4281288714 cites W3132722084 @default.
- W4281288714 cites W3206534526 @default.
- W4281288714 cites W3215884806 @default.
- W4281288714 cites W4210988199 @default.
- W4281288714 cites W4300859885 @default.
- W4281288714 doi "https://doi.org/10.1021/acs.joc.2c00418" @default.
- W4281288714 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35605190" @default.
- W4281288714 hasPublicationYear "2022" @default.
- W4281288714 type Work @default.
- W4281288714 citedByCount "5" @default.
- W4281288714 countsByYear W42812887142022 @default.
- W4281288714 countsByYear W42812887142023 @default.
- W4281288714 crossrefType "journal-article" @default.
- W4281288714 hasAuthorship W4281288714A5018596226 @default.
- W4281288714 hasAuthorship W4281288714A5048355915 @default.
- W4281288714 hasAuthorship W4281288714A5073407872 @default.
- W4281288714 hasAuthorship W4281288714A5075511300 @default.
- W4281288714 hasAuthorship W4281288714A5087382230 @default.
- W4281288714 hasConcept C112423150 @default.
- W4281288714 hasConcept C134195300 @default.
- W4281288714 hasConcept C146686406 @default.
- W4281288714 hasConcept C161790260 @default.
- W4281288714 hasConcept C178790620 @default.
- W4281288714 hasConcept C185592680 @default.
- W4281288714 hasConcept C21951064 @default.