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- W4281551743 abstract "Catalyst-controlled site-selective activation of β- and γ-methylene carbon-hydrogen (C-H) bonds of free carboxylic acids is a long-standing challenge. Here we show that, with a pair of palladium catalysts assembled with quinoline-pyridone ligands of different chelate ring sizes, it is possible to perform highly site-selective monolactonization reactions with a wide range of dicarboxylic acids, generating structurally diverse and synthetically useful γ- and δ-lactones via site-selective β- or γ-methylene C-H activation. The remaining carboxyl group serves as a versatile linchpin for further synthetic applications, as demonstrated by the total synthesis of two natural products, myrotheciumone A and pedicellosine, from abundant dicarboxylic acids." @default.
- W4281551743 created "2022-05-27" @default.
- W4281551743 creator A5007008557 @default.
- W4281551743 creator A5069037135 @default.
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- W4281551743 date "2022-06-24" @default.
- W4281551743 modified "2023-10-10" @default.
- W4281551743 title "Catalyst-controlled site-selective methylene C–H lactonization of dicarboxylic acids" @default.
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- W4281551743 doi "https://doi.org/10.1126/science.abq3048" @default.
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