Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281556835> ?p ?o ?g. }
- W4281556835 endingPage "9074" @default.
- W4281556835 startingPage "9063" @default.
- W4281556835 abstract "Additives, such as ions, small molecules, and macromolecules, have been found to regulate the formation of CaCO3 and control its morphologies and properties. However, a single additive usually affects dominantly one process in CaCO3’s formation and is seldom found to significantly affect multiple CaCO3 formation processes. Here, we used in situ grazing incidence X-ray techniques to observe the heterogeneous formation of CaCO3 and found that a series of formation processes (i.e., nucleation, growth, and Ostwald ripening) were modulated by sulfate. In the nucleation process, increased interfacial free energy and bulk free energy cooperatively increased the nucleation barrier and decreased nucleation rates. In the growth process, sulfate reduced the electrostatic repulsion between CaCO3 precursors and nuclei, promoting CaCO3 growth. This influence on the growth counteracted the inhibition effect in the nucleation process, causing a nearly 100% increase in the volume of heterogeneously formed CaCO3. Meanwhile, adsorbed sulfate on CaCO3 nuclei may poison the surface of smaller CaCO3 nuclei, inhibiting Ostwald ripening. These revealed sulfate’s active roles in controlling CaCO3 formation advance our understanding of sulfate-incorporated biomineralization and scaling phenomena in natural and engineered aquatic environments." @default.
- W4281556835 created "2022-05-27" @default.
- W4281556835 creator A5000701998 @default.
- W4281556835 creator A5021612328 @default.
- W4281556835 creator A5041712316 @default.
- W4281556835 creator A5086708025 @default.
- W4281556835 date "2022-05-26" @default.
- W4281556835 modified "2023-09-27" @default.
- W4281556835 title "Process-Specific Effects of Sulfate on CaCO<sub>3</sub> Formation in Environmentally Relevant Systems" @default.
- W4281556835 cites W1623043991 @default.
- W4281556835 cites W1800651854 @default.
- W4281556835 cites W1974595472 @default.
- W4281556835 cites W1990250430 @default.
- W4281556835 cites W1993977688 @default.
- W4281556835 cites W2001439928 @default.
- W4281556835 cites W2006769626 @default.
- W4281556835 cites W2012179647 @default.
- W4281556835 cites W2018809891 @default.
- W4281556835 cites W2020041075 @default.
- W4281556835 cites W2021612601 @default.
- W4281556835 cites W2030994386 @default.
- W4281556835 cites W2033443500 @default.
- W4281556835 cites W2034479558 @default.
- W4281556835 cites W2036807578 @default.
- W4281556835 cites W2042835484 @default.
- W4281556835 cites W2043501283 @default.
- W4281556835 cites W2048608493 @default.
- W4281556835 cites W2052109573 @default.
- W4281556835 cites W2052372268 @default.
- W4281556835 cites W2053166963 @default.
- W4281556835 cites W2054959591 @default.
- W4281556835 cites W2059232816 @default.
- W4281556835 cites W2059695310 @default.
- W4281556835 cites W2069672475 @default.
- W4281556835 cites W2076301558 @default.
- W4281556835 cites W2079798371 @default.
- W4281556835 cites W2083112912 @default.
- W4281556835 cites W2084194851 @default.
- W4281556835 cites W2086184799 @default.
- W4281556835 cites W2094082807 @default.
- W4281556835 cites W2099542505 @default.
- W4281556835 cites W2113899014 @default.
- W4281556835 cites W2141409468 @default.
- W4281556835 cites W2147257097 @default.
- W4281556835 cites W2148161525 @default.
- W4281556835 cites W2148461222 @default.
- W4281556835 cites W2150479014 @default.
- W4281556835 cites W2158335116 @default.
- W4281556835 cites W2168649638 @default.
- W4281556835 cites W2177930435 @default.
- W4281556835 cites W2315372720 @default.
- W4281556835 cites W2318827386 @default.
- W4281556835 cites W2321225884 @default.
- W4281556835 cites W2331587191 @default.
- W4281556835 cites W2333565023 @default.
- W4281556835 cites W2491452132 @default.
- W4281556835 cites W2515332365 @default.
- W4281556835 cites W2586119628 @default.
- W4281556835 cites W2751363151 @default.
- W4281556835 cites W2763929415 @default.
- W4281556835 cites W2788953871 @default.
- W4281556835 cites W2889665192 @default.
- W4281556835 cites W2945068742 @default.
- W4281556835 cites W2953296882 @default.
- W4281556835 cites W3015454328 @default.
- W4281556835 cites W3041773269 @default.
- W4281556835 cites W3183698553 @default.
- W4281556835 doi "https://doi.org/10.1021/acs.est.1c08898" @default.
- W4281556835 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35617118" @default.
- W4281556835 hasPublicationYear "2022" @default.
- W4281556835 type Work @default.
- W4281556835 citedByCount "6" @default.
- W4281556835 countsByYear W42815568352022 @default.
- W4281556835 countsByYear W42815568352023 @default.
- W4281556835 crossrefType "journal-article" @default.
- W4281556835 hasAuthorship W4281556835A5000701998 @default.
- W4281556835 hasAuthorship W4281556835A5021612328 @default.
- W4281556835 hasAuthorship W4281556835A5041712316 @default.
- W4281556835 hasAuthorship W4281556835A5086708025 @default.
- W4281556835 hasConcept C127413603 @default.
- W4281556835 hasConcept C159467904 @default.
- W4281556835 hasConcept C171250308 @default.
- W4281556835 hasConcept C178790620 @default.
- W4281556835 hasConcept C183586093 @default.
- W4281556835 hasConcept C185592680 @default.
- W4281556835 hasConcept C192562407 @default.
- W4281556835 hasConcept C2778343803 @default.
- W4281556835 hasConcept C42360764 @default.
- W4281556835 hasConcept C61048295 @default.
- W4281556835 hasConcept C62129180 @default.
- W4281556835 hasConceptScore W4281556835C127413603 @default.
- W4281556835 hasConceptScore W4281556835C159467904 @default.
- W4281556835 hasConceptScore W4281556835C171250308 @default.
- W4281556835 hasConceptScore W4281556835C178790620 @default.
- W4281556835 hasConceptScore W4281556835C183586093 @default.
- W4281556835 hasConceptScore W4281556835C185592680 @default.
- W4281556835 hasConceptScore W4281556835C192562407 @default.
- W4281556835 hasConceptScore W4281556835C2778343803 @default.