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- W4281560054 abstract "Abstract With the discovery of late transition metal platforms that support clean photoreductive halogen eliminations, we now describe an indazol‐3‐ylidene gold trichloride complex ([ 7 ] + ) decorated at the 4‐position by a xanthylium unit. This orange complex features a low energy band in the visible part of the spectrum, assigned to the charge transfer excitation of the indazol‐3‐ylidene/xanthylium donor/acceptor dyad. Green‐light irradiation of this complex in the presence of a chlorine trap elicits the clean photoelimination of chlorine radicals, producing the corresponding gold(I) complex. This visible‐light‐induced photoreduction is very efficient, reaching quantum yields close to 10 %. A neutral analog of [ 7 ] + featuring an anthryl group rather than a xanthylium unit proved to be perfectly photostable, supporting the importance of the xanthylium‐based photoredox unit present in [ 7 ] + ." @default.
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- W4281560054 date "2022-06-22" @default.
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- W4281560054 title "Green‐Light‐Driven Reductive Elimination of Chlorine from a Carbene‐Xanthylium Gold(III) Complex" @default.
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- W4281560054 doi "https://doi.org/10.1002/ange.202206265" @default.
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