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- W4281567494 abstract "We describe a new type of nitrenium-based Lewis acids: tetraaryl-1,2,3-triazolium salts. These were fully characterized by NMR and X-ray crystallography. The Gutmann-Beckett acidity numbers were determined to be up to 35.6, which is high compared to those of previously studied nitrenium salts. These salts catalyze the facile hydrosilylation-deoxygenation of ketones, aldehydes, acetals, alcohols, ethers, and silyl ethers under mild conditions in excellent yields. To our knowledge, this represents a first example of triazolium ions used as Lewis acid catalysts." @default.
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- W4281567494 date "2022-05-26" @default.
- W4281567494 modified "2023-10-11" @default.
- W4281567494 title "Triazolium Salts as Lewis Acid Catalysts" @default.
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- W4281567494 doi "https://doi.org/10.1021/acs.orglett.2c01108" @default.
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