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- W4281570985 abstract "Abstract The ylide‐functionalized diisopropyl phosphine (prYPhos) promotes Pd‐catalyzed Suzuki‐Miyaura couplings of aryl chlorides and bromides with arylboronic acids. Using Pd 2 (dba) 3 /prYPhos as the catalyst and K 2 CO 3 as the base, various (hetero)biaryls were synthesized in 45–98% yields at mild reaction conditions, tolerating sensitive functional groups and steric hindrance. The electron rich, sterically demanding ligand induces a high selectivity for halides versus triflate. Chloroaryl triflates were selectively coupled at the chloride, leaving inherently more reactive triflate groups in place. magnified image" @default.
- W4281570985 created "2022-05-27" @default.
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- W4281570985 date "2022-06-08" @default.
- W4281570985 modified "2023-10-03" @default.
- W4281570985 title "Ylide‐Functionalized Diisopropyl Phosphine (prYPhos): A Ligand for Selective Suzuki‐Miyaura Couplings of Aryl Chlorides" @default.
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- W4281570985 doi "https://doi.org/10.1002/adsc.202200321" @default.
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