FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281640895> ?p ?o ?g. }

• W4281640895 endingPage "8618" @default.
• W4281640895 startingPage "8557" @default.
• W4281640895 abstract "Direct conversion of methane (CH4) to C1–2 liquid oxygenates is a captivating approach to lock carbons in transportable value-added chemicals, while reducing global warming. Existing approaches utilizing the transformation of CH4 to liquid fuel via tandemized steam methane reforming and the Fischer–Tropsch synthesis are energy and capital intensive. Chemocatalytic partial oxidation of methane remains challenging due to the negligible electron affinity, poor C–H bond polarizability, and high activation energy barrier. Transition-metal and stoichiometric catalysts utilizing harsh oxidants and reaction conditions perform poorly with randomized product distribution. Paradoxically, the catalysts which are active enough to break C–H also promote overoxidation, resulting in CO2 generation and reduced carbon balance. Developing catalysts which can break C–H bonds of methane to selectively make useful chemicals at mild conditions is vital to commercialization. Single atom catalysts (SACs) with specifically coordinated metal centers on active support have displayed intrigued reactivity and selectivity for methane oxidation. SACs can significantly reduce the activation energy due to induced electrostatic polarization of the C–H bond to facilitate the accelerated reaction rate at the low reaction temperature. The distinct metal–support interaction can stabilize the intermediate and prevent the overoxidation of the reaction products. The present review accounts for recent progress in the field of SACs for the selective oxidation of CH4 to C1–2 oxygenates. The chemical nature of catalytic sites, effects of metal–support interaction, and stabilization of intermediate species on catalysts to minimize overoxidation are thoroughly discussed with a forward-looking perspective to improve the catalytic performance." @default.
• W4281640895 created "2022-06-13" @default.
• W4281640895 creator A5034642948 @default.
• W4281640895 creator A5054125941 @default.
• W4281640895 creator A5072919054 @default.
• W4281640895 creator A5074155172 @default.
• W4281640895 date "2022-05-31" @default.
• W4281640895 modified "2023-10-18" @default.
• W4281640895 title "Single Atom Catalysts for Selective Methane Oxidation to Oxygenates" @default.
• W4281640895 cites W1209331024 @default.
• W4281640895 cites W1934994973 @default.
• W4281640895 cites W1966278195 @default.
• W4281640895 cites W1969362431 @default.
• W4281640895 cites W1970595046 @default.
• W4281640895 cites W1977204727 @default.
• W4281640895 cites W1979371521 @default.
• W4281640895 cites W1980531411 @default.
• W4281640895 cites W1980869920 @default.
• W4281640895 cites W1981763423 @default.
• W4281640895 cites W1984306479 @default.
• W4281640895 cites W1988726984 @default.
• W4281640895 cites W1988767107 @default.
• W4281640895 cites W1990042917 @default.
• W4281640895 cites W1992277893 @default.
• W4281640895 cites W1993459929 @default.
• W4281640895 cites W1999943753 @default.
• W4281640895 cites W2000705499 @default.
• W4281640895 cites W2004548388 @default.
• W4281640895 cites W2007290686 @default.
• W4281640895 cites W2011855795 @default.
• W4281640895 cites W2012137813 @default.
• W4281640895 cites W2012892074 @default.
• W4281640895 cites W2013187757 @default.
• W4281640895 cites W2018032840 @default.
• W4281640895 cites W2023169889 @default.
• W4281640895 cites W2024756826 @default.
• W4281640895 cites W2025479583 @default.
• W4281640895 cites W2025495062 @default.
• W4281640895 cites W2026650491 @default.
• W4281640895 cites W2026934868 @default.
• W4281640895 cites W2030467995 @default.
• W4281640895 cites W2030933039 @default.
• W4281640895 cites W2041075595 @default.
• W4281640895 cites W2041721340 @default.
• W4281640895 cites W2042545763 @default.
• W4281640895 cites W2045528116 @default.
• W4281640895 cites W2048932034 @default.
• W4281640895 cites W2053154108 @default.
• W4281640895 cites W2056257661 @default.
• W4281640895 cites W2066606143 @default.
• W4281640895 cites W2067859522 @default.
• W4281640895 cites W2068648274 @default.
• W4281640895 cites W2068798141 @default.
• W4281640895 cites W2069503178 @default.
• W4281640895 cites W2071106678 @default.
• W4281640895 cites W2074717643 @default.
• W4281640895 cites W2075758526 @default.
• W4281640895 cites W2076842204 @default.
• W4281640895 cites W2078126741 @default.
• W4281640895 cites W2078385084 @default.
• W4281640895 cites W2078434204 @default.
• W4281640895 cites W2083322390 @default.
• W4281640895 cites W2086564895 @default.
• W4281640895 cites W2097930656 @default.
• W4281640895 cites W2098864517 @default.
• W4281640895 cites W2100513083 @default.
• W4281640895 cites W2101694328 @default.
• W4281640895 cites W2113854836 @default.
• W4281640895 cites W2115870669 @default.
• W4281640895 cites W2119319723 @default.
• W4281640895 cites W2120478834 @default.
• W4281640895 cites W2121319171 @default.
• W4281640895 cites W2132759228 @default.
• W4281640895 cites W2134716155 @default.
• W4281640895 cites W2136979823 @default.
• W4281640895 cites W2147899939 @default.
• W4281640895 cites W2151516307 @default.
• W4281640895 cites W2154218705 @default.
• W4281640895 cites W2162783646 @default.
• W4281640895 cites W2163591521 @default.
• W4281640895 cites W2164096075 @default.
• W4281640895 cites W2166160854 @default.
• W4281640895 cites W2181522365 @default.
• W4281640895 cites W2226406645 @default.
• W4281640895 cites W2298210409 @default.
• W4281640895 cites W2322912842 @default.
• W4281640895 cites W2323095200 @default.
• W4281640895 cites W2324145846 @default.
• W4281640895 cites W2328661249 @default.
• W4281640895 cites W2328823332 @default.
• W4281640895 cites W2332047839 @default.
• W4281640895 cites W2333096653 @default.
• W4281640895 cites W2333197797 @default.
• W4281640895 cites W2336081837 @default.
• W4281640895 cites W2344292205 @default.
• W4281640895 cites W2407781020 @default.
• W4281640895 cites W2432848579 @default.
• W4281640895 cites W2437871588 @default.

• next