Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281661990> ?p ?o ?g. }
- W4281661990 endingPage "7003" @default.
- W4281661990 startingPage "6997" @default.
- W4281661990 abstract "We report a direct tandem C–O/C–H activation approach to C–C bond formation using palladium catalysis. This reaction combines C–O oxidative addition at enol pivalates with concerted metalation–deprotonation of functionalized heterocycles to achieve base-free direct C–H alkenylation. Preliminary mechanistic studies revealed that the C–O oxidative addition to Pd(0) is reversible under these conditions and that C–H activation occurs directly from the Pd(II) C–O oxidative addition product. In situ 31P NMR spectroscopy further revealed that the (Cy3P)2Pd(alkenyl)(OPiv) species is a major catalyst resting state during the reactions." @default.
- W4281661990 created "2022-06-13" @default.
- W4281661990 creator A5025154329 @default.
- W4281661990 creator A5041546833 @default.
- W4281661990 creator A5068970719 @default.
- W4281661990 creator A5072369886 @default.
- W4281661990 creator A5076644996 @default.
- W4281661990 creator A5084174089 @default.
- W4281661990 date "2022-05-31" @default.
- W4281661990 modified "2023-09-30" @default.
- W4281661990 title "Palladium-Catalyzed Direct C–H Alkenylation with Enol Pivalates Proceeds via Reversible C–O Oxidative Addition to Pd(0)" @default.
- W4281661990 cites W1878527273 @default.
- W4281661990 cites W1936696905 @default.
- W4281661990 cites W1980410060 @default.
- W4281661990 cites W1984703406 @default.
- W4281661990 cites W2000128109 @default.
- W4281661990 cites W2001545291 @default.
- W4281661990 cites W2003850217 @default.
- W4281661990 cites W2006162336 @default.
- W4281661990 cites W2006594496 @default.
- W4281661990 cites W2024983608 @default.
- W4281661990 cites W2025953209 @default.
- W4281661990 cites W2028824397 @default.
- W4281661990 cites W2030346470 @default.
- W4281661990 cites W2032731092 @default.
- W4281661990 cites W2067433167 @default.
- W4281661990 cites W2077950534 @default.
- W4281661990 cites W2079050104 @default.
- W4281661990 cites W2081973200 @default.
- W4281661990 cites W2097184152 @default.
- W4281661990 cites W2098665439 @default.
- W4281661990 cites W2101897276 @default.
- W4281661990 cites W2109515899 @default.
- W4281661990 cites W2125014016 @default.
- W4281661990 cites W2144697473 @default.
- W4281661990 cites W2162667052 @default.
- W4281661990 cites W2170647440 @default.
- W4281661990 cites W2312484018 @default.
- W4281661990 cites W2317144448 @default.
- W4281661990 cites W2317296363 @default.
- W4281661990 cites W2325956918 @default.
- W4281661990 cites W2328665883 @default.
- W4281661990 cites W2331162383 @default.
- W4281661990 cites W2335578790 @default.
- W4281661990 cites W2339051409 @default.
- W4281661990 cites W2402407520 @default.
- W4281661990 cites W2407010107 @default.
- W4281661990 cites W2462322978 @default.
- W4281661990 cites W2463638842 @default.
- W4281661990 cites W2528333019 @default.
- W4281661990 cites W2561515125 @default.
- W4281661990 cites W2616399381 @default.
- W4281661990 cites W2732218143 @default.
- W4281661990 cites W2796526806 @default.
- W4281661990 cites W2898332811 @default.
- W4281661990 cites W2903817531 @default.
- W4281661990 cites W2905686003 @default.
- W4281661990 cites W2911199588 @default.
- W4281661990 cites W2944148756 @default.
- W4281661990 cites W2995096834 @default.
- W4281661990 cites W3036410957 @default.
- W4281661990 cites W3082601917 @default.
- W4281661990 cites W3087117600 @default.
- W4281661990 cites W3104254883 @default.
- W4281661990 cites W3127984306 @default.
- W4281661990 cites W3128724272 @default.
- W4281661990 cites W3133179163 @default.
- W4281661990 cites W3139240968 @default.
- W4281661990 cites W3158544329 @default.
- W4281661990 cites W3168224616 @default.
- W4281661990 cites W3173857875 @default.
- W4281661990 cites W3184103699 @default.
- W4281661990 cites W3198392325 @default.
- W4281661990 cites W3203305025 @default.
- W4281661990 cites W4226427689 @default.
- W4281661990 cites W4253325469 @default.
- W4281661990 cites W4365922187 @default.
- W4281661990 cites W3017197847 @default.
- W4281661990 doi "https://doi.org/10.1021/acscatal.2c01305" @default.
- W4281661990 hasPublicationYear "2022" @default.
- W4281661990 type Work @default.
- W4281661990 citedByCount "3" @default.
- W4281661990 countsByYear W42816619902023 @default.
- W4281661990 crossrefType "journal-article" @default.
- W4281661990 hasAuthorship W4281661990A5025154329 @default.
- W4281661990 hasAuthorship W4281661990A5041546833 @default.
- W4281661990 hasAuthorship W4281661990A5068970719 @default.
- W4281661990 hasAuthorship W4281661990A5072369886 @default.
- W4281661990 hasAuthorship W4281661990A5076644996 @default.
- W4281661990 hasAuthorship W4281661990A5084174089 @default.
- W4281661990 hasConcept C118629725 @default.
- W4281661990 hasConcept C145148216 @default.
- W4281661990 hasConcept C155647269 @default.
- W4281661990 hasConcept C161790260 @default.
- W4281661990 hasConcept C178790620 @default.
- W4281661990 hasConcept C185592680 @default.
- W4281661990 hasConcept C2775855785 @default.
- W4281661990 hasConcept C2777495281 @default.