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- W4281662787 abstract "Anchoring of transition metal phosphides as cocatalysts onto the electron outlet of photocatalytically active systems demonstrates the unprecedented potential for increasing the rate of photocatalytic hydrogen generation. Herein, the role of NiP nanoparticles as cocatalysts for enhancing the charge transfer mechanism towards photocatalytic hydrogen generation is explored. A general chemical deposition strategy is adopted for the controlled surface anchoring of NiP cocatalyst onto the photocatalytic system, and the obtained NiP anchored photocatalyst is found to exhibit superior photocatalytic performance towards visible light driven water splitting. The enhanced photocatalytic activity is attributed to the synergistic interaction of NiP cocatalysts to facilitate strong electronic interactions at the heterojunctions, which are beneficial for the rapid transfer of photogenerated electrons to protons. The present approach may widen the horizon for design of many other noble-metal-free metal phosphides as highly efficient cocatalysts for photocatalytic hydrogen generation. Photocatalytic hydrogen generation of NiP30@Fe 2 O 3 –TiO 2 under visible light irradiation. • A cocatalytic integration strategy of anchoring NiP cocatalysts is explored. • The charge separation efficiency at the heterojunctions is enhanced effectually. • NiP act as redox reaction sites to catalyze the water splitting reaction. • NiP advanced the synergism of heterojunctions for an enhanced photocatalysis." @default.
- W4281662787 created "2022-06-13" @default.
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- W4281662787 date "2022-07-01" @default.
- W4281662787 modified "2023-10-17" @default.
- W4281662787 title "Interfacial charge separation of nickel phosphide anchored on anatase-hematite heterojunction for stimulating visible light driven hydrogen generation" @default.
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- W4281662787 doi "https://doi.org/10.1016/j.ijhydene.2022.05.148" @default.
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