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• W4281683556 abstract "In this paper, we report the synthesis and structural characterisation of two hetero-metallic clusters, [(CO)3CrSn5Cr(CO)3]4− and [(CO)3MoSn5Mo(CO)3]4−, both of which have a pentagonal bipyramidal core. The structures are similar to that of previously reported [(CO)3MoPb5Mo(CO)3]4− and our analysis of the bonding suggests that they are best formulated as containing Sn54− rings bridging two zerovalent M(CO)3 fragments. The electronic structure is compared to two isolobal M2E5 clusters, [CpCrP5CrCp]− and Tl77−, both of which show clear evidence for trans-annular bonds between the apical atoms that is not immediately obvious in the title clusters. Our analysis shows that the balance between E-E and M-M bonding is a delicate one, and shifts in the relative energies of the orbitals on the E5 and M2 fragments generate a continuum of bonding situations linked by the degree of localisation of the cluster LUMO." @default.
• W4281683556 created "2022-06-13" @default.
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• W4281683556 date "2022-05-30" @default.
• W4281683556 modified "2023-10-14" @default.
• W4281683556 title "Synthesis, Structure and Bonding in Pentagonal Bipyramidal Cluster Compounds Containing a cyclo-Sn5 Ring, [(CO)3MSn5M(CO)3]4− (M = Cr, Mo)" @default.
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• W4281683556 doi "https://doi.org/10.3390/inorganics10060075" @default.
• W4281683556 hasPublicationYear "2022" @default.
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