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- W4281693048 abstract "Abstract In the absence of transition-metal catalysts and additional oxidants, arylhydroxylamines can undergo an unconventional O-sulfinylation/[2,3]-sigmatropic rearrangement/rearomatization cascade with trifluoromethylsulfinyl chloride to rapidly and efficiently synthesize versatile ortho-sulfonylated aromatic amines. This Synpacts article describes the discovery, further study, and practical application of the rearrangement reactions in arylhydroxylamine compounds and highlights our recent advances in this area. 1 Introduction 2 Discovery of a New Reaction 3 O-Sulfinylation of Arylhydroxylamines Followed by [2,3]-σ Rearrangement 4 Conclusion" @default.
- W4281693048 created "2022-06-13" @default.
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- W4281693048 date "2022-05-30" @default.
- W4281693048 modified "2023-09-25" @default.
- W4281693048 title "[2,3]-Sigmatropic Rearrangement of Arylhydroxylamines: Rapid Access to ortho-Sulfonylated Anilines" @default.
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- W4281693048 doi "https://doi.org/10.1055/a-1863-9090" @default.
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