Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281695384> ?p ?o ?g. }
- W4281695384 abstract "Abstract A series of rhodium and iridium complexes with a N‐heterocyclic carbene (NHC) ligand decorated with a perylene‐diimide‐pyrene moiety are described. Electrochemical studies reveal that the complexes can undergo two successive one‐electron reduction events, associated to the reduction of the PDI moiety attached to the NHC ligand. The reduction of the ligand produces a significant increase on its electron‐donating character, as observed from the infrared spectroelectrochemical studies. The rhodium complex was tested in the [3+2] cycloaddition of diphenylcyclopropenone and methylphenylacetylene, where it displayed a redox‐switchable behavior. The neutral complex showed moderate activity, which was suppressed when the catalyst was reduced." @default.
- W4281695384 created "2022-06-13" @default.
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- W4281695384 creator A5064156685 @default.
- W4281695384 date "2022-06-16" @default.
- W4281695384 modified "2023-10-16" @default.
- W4281695384 title "Redox‐Switchable Complexes Based on Nanographene‐NHCs" @default.
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- W4281695384 doi "https://doi.org/10.1002/chem.202201384" @default.
- W4281695384 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35638131" @default.
- W4281695384 hasPublicationYear "2022" @default.