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- W4281717745 endingPage "2306" @default.
- W4281717745 startingPage "2289" @default.
- W4281717745 abstract "Abstract Heterocyclic N ‐oxides are prevalent in numerous natural products with broad applications in pharmaceuticals, agrochemicals, material sciences, and asymmetric synthesis. Owing to their profound biological and physiological activity and unique chemical reactivity, the importance of these compounds has stimulated substantial interest among organic synthetic chemists. More importantly, C‐2 functionalization of heterocyclic N ‐oxides, including pyridine‐, isoquinoline‐, pyrazine‐, quinoxaline‐, and quinoline N ‐oxides, is among the most important strategies for heterocyclic functionalization. Besides, deoxygenation of heterocyclic N ‐oxides has also emerged as a reaction of significance in organic chemistry. In the past decade, visible light photoredox catalyzed C‐2 functionalization and deoxygenation of these heterocyclic N ‐oxides have drawn substantial attention owing to their mild reaction conditions. This review has been categorized based on visible‐light‐mediated nondeoxygenative C‐2 functionalization (alkylation, fluoroalkylation, arylation, acylation, and amination), deoxygenative C‐2 functionalization (sulfonylation, alkynylation, alkylation, and acylation), and deoxygenation (without C−H functionalization) of heterocyclic N ‐oxides. For most part of the work, the substrate scope, limitation, and mechanism of the reactions have been discussed. magnified image" @default.
- W4281717745 created "2022-06-13" @default.
- W4281717745 creator A5034879719 @default.
- W4281717745 creator A5073448423 @default.
- W4281717745 creator A5085052920 @default.
- W4281717745 date "2022-06-23" @default.
- W4281717745 modified "2023-10-16" @default.
- W4281717745 title "Visible‐Light‐Mediated C‐2 Functionalization and Deoxygenative Strategies in Heterocyclic <i>N</i>‐Oxides" @default.
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