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• W4281755613 startingPage "111877" @default.
• W4281755613 abstract "In this work, we report on the development of fluorescent half-sandwich iridium complexes using a fluorophore attachment strategy. These constructs consist of pentamethylcyclopentadienyl (Cp*) iridium units ligated by picolinamidate donors conjugated to green-emitting boron-dipyrromethene (bodipy) dyes. Reaction studies in H2O/THF mixtures showed that the fluorescent Ir complexes were active as catalysts for transfer hydrogenation, with activities similar to that of their non-fluorescent counterparts. The iridium complexes were taken up by NIH-3T3 mouse fibroblast cells, with 50% inhibition concentrations ranging from ~20–70 μM after exposure for 3 h. Visualization of the bodipy-functionalized Ir complexes in cells using fluorescence microscopy revealed that they were localized in the mitochondria and lysosome but not the nucleus. These results indicate that our fluorescent iridium complexes could be useful for future biological studies requiring intracellular catalyst tracking." @default.
• W4281755613 created "2022-06-13" @default.
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• W4281755613 date "2022-09-01" @default.
• W4281755613 modified "2023-09-28" @default.
• W4281755613 title "Fluorescent half-sandwich iridium picolinamidate complexes for in-cell visualization" @default.
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• W4281755613 doi "https://doi.org/10.1016/j.jinorgbio.2022.111877" @default.
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