Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281774452> ?p ?o ?g. }
- W4281774452 endingPage "140694" @default.
- W4281774452 startingPage "140694" @default.
- W4281774452 abstract "Conversion-type transition metal oxides (TMOs) anodes with fascinating high theoretical capacities are considered potential candidates for high-energy-density alkali-ion batteries. However, the tremendous advantages of conversion reaction are yet to be fully exploited due to sluggish reaction kinetics and unfavorable thermodynamics. This is especially in the case of non-layered TMOs, where high ion intercalation energy and ion diffusion barriers compared to layered TMOs impede subsequent conversion reaction, while thermodynamically stable metal-oxide bonds with high bond energies prevent efficient cleavage. This work selects MoO2 as a typical non-layered anode of lithium-ion batteries and demonstrates that pre-intercalating K+ ions in MoO2 crystal can decrease the intercalation energy, enhance the diffusion kinetics, and weaken Mo-O bonds to efficiently facilitate conversion reactions by the the density functional theory calculations and experiments. K+ pre-intercalated MoO2 can deliver a higher reversible discharge specific capacity (989 mAh g−1) than the pristine MoO2 sample (720 mAh g−1) at 0.2 A g−1 after 100 cycles. This work provides a novel and crucial method to realize the functionality of non-layered TMOs based anodes and offers a potentially universal optimization strategy toward high-capacity alkali-ion batteries." @default.
- W4281774452 created "2022-06-13" @default.
- W4281774452 creator A5016438972 @default.
- W4281774452 creator A5020782118 @default.
- W4281774452 creator A5047279517 @default.
- W4281774452 creator A5052676364 @default.
- W4281774452 creator A5056626020 @default.
- W4281774452 creator A5058719264 @default.
- W4281774452 creator A5062895804 @default.
- W4281774452 creator A5065309116 @default.
- W4281774452 creator A5087592842 @default.
- W4281774452 date "2022-09-01" @default.
- W4281774452 modified "2023-10-14" @default.
- W4281774452 title "Enabling deep conversion reactions by weakening molybdenum-oxygen bonds through K+ pre-intercalation" @default.
- W4281774452 cites W1970320842 @default.
- W4281774452 cites W1981368803 @default.
- W4281774452 cites W2007395042 @default.
- W4281774452 cites W2016895472 @default.
- W4281774452 cites W2035297392 @default.
- W4281774452 cites W2060315855 @default.
- W4281774452 cites W2063031073 @default.
- W4281774452 cites W2071792132 @default.
- W4281774452 cites W2083222334 @default.
- W4281774452 cites W2083750854 @default.
- W4281774452 cites W2094560360 @default.
- W4281774452 cites W2097593048 @default.
- W4281774452 cites W2122427541 @default.
- W4281774452 cites W2130991433 @default.
- W4281774452 cites W2138132681 @default.
- W4281774452 cites W2312321370 @default.
- W4281774452 cites W2313093715 @default.
- W4281774452 cites W2316136926 @default.
- W4281774452 cites W2333977535 @default.
- W4281774452 cites W2337381778 @default.
- W4281774452 cites W2529759014 @default.
- W4281774452 cites W2672130116 @default.
- W4281774452 cites W2810836439 @default.
- W4281774452 cites W2891971754 @default.
- W4281774452 cites W2901401504 @default.
- W4281774452 cites W2903129444 @default.
- W4281774452 cites W2903335095 @default.
- W4281774452 cites W2906798185 @default.
- W4281774452 cites W2908245269 @default.
- W4281774452 cites W2908542802 @default.
- W4281774452 cites W2924361956 @default.
- W4281774452 cites W2944190071 @default.
- W4281774452 cites W2956122938 @default.
- W4281774452 cites W2995211985 @default.
- W4281774452 cites W3023435578 @default.
- W4281774452 cites W3048572533 @default.
- W4281774452 cites W3080374858 @default.
- W4281774452 cites W3090962012 @default.
- W4281774452 cites W3098025825 @default.
- W4281774452 cites W3156577582 @default.
- W4281774452 cites W3186396051 @default.
- W4281774452 cites W4210789658 @default.
- W4281774452 cites W4238154726 @default.
- W4281774452 doi "https://doi.org/10.1016/j.electacta.2022.140694" @default.
- W4281774452 hasPublicationYear "2022" @default.
- W4281774452 type Work @default.
- W4281774452 citedByCount "0" @default.
- W4281774452 crossrefType "journal-article" @default.
- W4281774452 hasAuthorship W4281774452A5016438972 @default.
- W4281774452 hasAuthorship W4281774452A5020782118 @default.
- W4281774452 hasAuthorship W4281774452A5047279517 @default.
- W4281774452 hasAuthorship W4281774452A5052676364 @default.
- W4281774452 hasAuthorship W4281774452A5056626020 @default.
- W4281774452 hasAuthorship W4281774452A5058719264 @default.
- W4281774452 hasAuthorship W4281774452A5062895804 @default.
- W4281774452 hasAuthorship W4281774452A5065309116 @default.
- W4281774452 hasAuthorship W4281774452A5087592842 @default.
- W4281774452 hasConcept C106773901 @default.
- W4281774452 hasConcept C121332964 @default.
- W4281774452 hasConcept C127413603 @default.
- W4281774452 hasConcept C134018914 @default.
- W4281774452 hasConcept C137824038 @default.
- W4281774452 hasConcept C145148216 @default.
- W4281774452 hasConcept C147597530 @default.
- W4281774452 hasConcept C147789679 @default.
- W4281774452 hasConcept C152365726 @default.
- W4281774452 hasConcept C161790260 @default.
- W4281774452 hasConcept C171250308 @default.
- W4281774452 hasConcept C17525397 @default.
- W4281774452 hasConcept C178790620 @default.
- W4281774452 hasConcept C179104552 @default.
- W4281774452 hasConcept C185592680 @default.
- W4281774452 hasConcept C192562407 @default.
- W4281774452 hasConcept C198091228 @default.
- W4281774452 hasConcept C2778541603 @default.
- W4281774452 hasConcept C2779851234 @default.
- W4281774452 hasConcept C42360764 @default.
- W4281774452 hasConcept C549387045 @default.
- W4281774452 hasConcept C69357855 @default.
- W4281774452 hasConcept C71924100 @default.
- W4281774452 hasConcept C89395315 @default.
- W4281774452 hasConcept C97355855 @default.
- W4281774452 hasConceptScore W4281774452C106773901 @default.
- W4281774452 hasConceptScore W4281774452C121332964 @default.