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- W4281781138 abstract "Abstract A single pot reaction of rhenium decacarbonyl, dipyrrinato ligand (5-(4-methylbenzoate)-dipyrromethene, L 1 H ) and an ancillary ligand (either triphenyl phosphine or pyridine) in mesitylene medium has yielded visible light absorbing complexes 1 and 2 having a general formula [L 1 Re(CO) 3 L 2 ] (L 1 = dipyrrinato ligand; L 2 = PPh 3 = 1 ; L 2 = pyridyl = 2 ). The complexes were characterized using IR UV-Vis, NMR and HRMS techniques. Binding of fac -Re(CO) 3 to L 1 H has significantly red-shifted the charge transfer band at 436 nm to 488-491 nm in the complexes 1 and 2 . Compound 1 is previously reported, although here we report a single step process that is different from the two-step process known in the literature." @default.
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- W4281781138 date "2022-05-01" @default.
- W4281781138 modified "2023-10-01" @default.
- W4281781138 title "Synthesis and Characterization of Dipyrrin Based fac-Re(CO)<sub>3</sub> Containing Complexes" @default.
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- W4281781138 doi "https://doi.org/10.1088/1742-6596/2267/1/012076" @default.
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