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- W4281785655 abstract "Abstract A novel EDA complex comprised of a bis(chlorodifluoroacetoxy)iodoarene and 1,3,5‐trimethoxybenzene is described, which enables the direct radical C(sp 2 )−H chlorodifluoromethylation of arenes and heteroarenes under monochromatic visible‐light irradiation. The procedure is mild, operationally simple, and utilizes commercially available reagents. The developed conditions demonstrate compatibility with a host of commonly encountered functionalities and biologically relevant scaffolds, whilst showcasing the post‐functionalization capabilities of the −CF 2 Cl moiety. Various mechanistic studies were performed to explore the EDA complex and radical generation pathway." @default.
- W4281785655 created "2022-06-13" @default.
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- W4281785655 date "2022-06-24" @default.
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- W4281785655 title "Visible Light‐Mediated Metal‐Free Chlorodifluoromethylation of Arenes and Heteroarenes by a Hypervalent Iodine EDA Complex" @default.
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- W4281785655 doi "https://doi.org/10.1002/ejoc.202200607" @default.
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