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- W4281788265 abstract "Aerosol chemistry has broad relevance for climate and global public health. The role of interfacial phenomena in condensed-phase aerosol reactions remains poorly understood. In this work, liquid drop formalisms are coupled with high-pressure transition state theory to formulate an expression for predicting the size-dependence of aerosol reaction rates and viscosity. Insights from high-pressure synthesis studies suggest that accretion and cyclization reactions are accelerated in 3–10-nm particles smaller than 10 nm. Reactions of peroxide, epoxide, furanoid, aldol, and carbonyl functional groups are accelerated by up to tenfold. Effective rate enhancements are ranked as: cycloadditions >> aldol reactions > epoxide reactions > Baeyer-Villiger oxidation >> imidazole formation (which is inhibited). Some reactions are enabled by the elevated pressure in particles. Viscosity increases for organic liquids but decreases for viscous or solid particles. Results suggest that internal pressure is an important consideration in studies of the physics and chemical evolution of nanoparticles." @default.
- W4281788265 created "2022-06-13" @default.
- W4281788265 creator A5034221807 @default.
- W4281788265 date "2022-06-13" @default.
- W4281788265 modified "2023-10-11" @default.
- W4281788265 title "Constraints on the Role of Laplace Pressure in Multiphase Reactions and Viscosity of Organic Aerosols" @default.
- W4281788265 cites W1512531242 @default.
- W4281788265 cites W1649740783 @default.
- W4281788265 cites W1666891192 @default.
- W4281788265 cites W1679483972 @default.
- W4281788265 cites W1712391879 @default.
- W4281788265 cites W1914941426 @default.
- W4281788265 cites W1923753509 @default.
- W4281788265 cites W1958787480 @default.
- W4281788265 cites W1966779205 @default.
- W4281788265 cites W1970035795 @default.
- W4281788265 cites W1974319499 @default.
- W4281788265 cites W1982969719 @default.
- W4281788265 cites W1988320097 @default.
- W4281788265 cites W1989849107 @default.
- W4281788265 cites W1994530887 @default.
- W4281788265 cites W1996244042 @default.
- W4281788265 cites W2011254556 @default.
- W4281788265 cites W2016632280 @default.
- W4281788265 cites W2021224521 @default.
- W4281788265 cites W2021986079 @default.
- W4281788265 cites W2022479138 @default.
- W4281788265 cites W2026129950 @default.
- W4281788265 cites W2036123490 @default.
- W4281788265 cites W2045617521 @default.
- W4281788265 cites W2047501559 @default.
- W4281788265 cites W2047926788 @default.
- W4281788265 cites W2049784649 @default.
- W4281788265 cites W2051383640 @default.
- W4281788265 cites W2052748907 @default.
- W4281788265 cites W2053027087 @default.
- W4281788265 cites W2053646993 @default.
- W4281788265 cites W2054666821 @default.
- W4281788265 cites W2057152777 @default.
- W4281788265 cites W2058938611 @default.
- W4281788265 cites W2061512577 @default.
- W4281788265 cites W2062509478 @default.
- W4281788265 cites W2063725653 @default.
- W4281788265 cites W2066887109 @default.
- W4281788265 cites W2068128923 @default.
- W4281788265 cites W2070568080 @default.
- W4281788265 cites W2072244200 @default.
- W4281788265 cites W2076685284 @default.
- W4281788265 cites W2079702179 @default.
- W4281788265 cites W2080848563 @default.
- W4281788265 cites W2087792308 @default.
- W4281788265 cites W2088657480 @default.
- W4281788265 cites W2090627946 @default.
- W4281788265 cites W2092039733 @default.
- W4281788265 cites W2093707369 @default.
- W4281788265 cites W2095118371 @default.
- W4281788265 cites W2101922791 @default.
- W4281788265 cites W2103639584 @default.
- W4281788265 cites W2106612002 @default.
- W4281788265 cites W2108291093 @default.
- W4281788265 cites W2109358553 @default.
- W4281788265 cites W2117004231 @default.
- W4281788265 cites W2122054302 @default.
- W4281788265 cites W2127903053 @default.
- W4281788265 cites W2129628802 @default.
- W4281788265 cites W2132869159 @default.
- W4281788265 cites W2136169675 @default.
- W4281788265 cites W2138736664 @default.
- W4281788265 cites W2142698232 @default.
- W4281788265 cites W2145958898 @default.
- W4281788265 cites W2148635929 @default.
- W4281788265 cites W2156564154 @default.
- W4281788265 cites W2163144959 @default.
- W4281788265 cites W2169327170 @default.
- W4281788265 cites W2174196825 @default.
- W4281788265 cites W2262384140 @default.
- W4281788265 cites W2298456115 @default.
- W4281788265 cites W2307226936 @default.
- W4281788265 cites W2312715874 @default.
- W4281788265 cites W2324190200 @default.
- W4281788265 cites W2324318123 @default.
- W4281788265 cites W2333397163 @default.
- W4281788265 cites W2333702265 @default.
- W4281788265 cites W2336003706 @default.
- W4281788265 cites W2402503711 @default.
- W4281788265 cites W2402991992 @default.
- W4281788265 cites W2501780157 @default.
- W4281788265 cites W2507780804 @default.
- W4281788265 cites W2525319129 @default.
- W4281788265 cites W2531509142 @default.
- W4281788265 cites W2543188336 @default.
- W4281788265 cites W2559019432 @default.
- W4281788265 cites W2587661038 @default.
- W4281788265 cites W2606924987 @default.
- W4281788265 cites W2608253988 @default.
- W4281788265 cites W2655264143 @default.
- W4281788265 cites W2727678863 @default.
- W4281788265 cites W2727690471 @default.
- W4281788265 cites W2739467445 @default.
- W4281788265 cites W2740169047 @default.