Matches in SemOpenAlex for { <https://semopenalex.org/work/W4281870178> ?p ?o ?g. }
- W4281870178 abstract "A straightforward synthetic protocol leading to carbene-metal-amido (CMA) complexes (metal=Au, Cu) using a mild base and an environmentally desirable solvent (EtOH) has been explored, with a focus on complexes bearing backbone-substituted N-heterocyclic carbene (NHC) ligands, including BIAN-NHCs (BIAN=bis(imino)acenaphthene). The novel CMAs were structurally characterized, and gold-based CMAs bearing diverse NHCs were screened as simple, Brønsted-basic precatalysts. The readily accessible complexes display high catalytic activity in the intermolecular and intramolecular hydrocarboxylation of internal alkynes and alkynoic acids respectively, while the screening reveals the ancillary ligand effect of NHCs in these catalytic systems." @default.
- W4281870178 created "2022-06-13" @default.
- W4281870178 creator A5006345917 @default.
- W4281870178 creator A5010800024 @default.
- W4281870178 creator A5013572658 @default.
- W4281870178 creator A5027363854 @default.
- W4281870178 creator A5048424168 @default.
- W4281870178 creator A5060095091 @default.
- W4281870178 creator A5068366778 @default.
- W4281870178 creator A5072418754 @default.
- W4281870178 creator A5088557661 @default.
- W4281870178 date "2022-07-06" @default.
- W4281870178 modified "2023-10-01" @default.
- W4281870178 title "Synthesis of Carbene‐Metal‐Amido (CMA) Complexes and Their Use as Precatalysts for the Activator‐Free, Gold‐Catalyzed Addition of Carboxylic Acids to Alkynes" @default.
- W4281870178 cites W181142859 @default.
- W4281870178 cites W1965065305 @default.
- W4281870178 cites W1968507581 @default.
- W4281870178 cites W2011346498 @default.
- W4281870178 cites W2020028678 @default.
- W4281870178 cites W2025002140 @default.
- W4281870178 cites W2028803879 @default.
- W4281870178 cites W2032908754 @default.
- W4281870178 cites W2034584015 @default.
- W4281870178 cites W2044673682 @default.
- W4281870178 cites W2049249446 @default.
- W4281870178 cites W2052178447 @default.
- W4281870178 cites W2057419595 @default.
- W4281870178 cites W2078790658 @default.
- W4281870178 cites W2092607672 @default.
- W4281870178 cites W2097380884 @default.
- W4281870178 cites W2120487222 @default.
- W4281870178 cites W2121970136 @default.
- W4281870178 cites W2122706087 @default.
- W4281870178 cites W2135657785 @default.
- W4281870178 cites W2136241608 @default.
- W4281870178 cites W2150933537 @default.
- W4281870178 cites W2155284846 @default.
- W4281870178 cites W2158167834 @default.
- W4281870178 cites W2160574842 @default.
- W4281870178 cites W2166144166 @default.
- W4281870178 cites W2323176197 @default.
- W4281870178 cites W2328404200 @default.
- W4281870178 cites W2334067119 @default.
- W4281870178 cites W2334656961 @default.
- W4281870178 cites W2339829844 @default.
- W4281870178 cites W2470659897 @default.
- W4281870178 cites W2518142739 @default.
- W4281870178 cites W2552335991 @default.
- W4281870178 cites W2560612120 @default.
- W4281870178 cites W2582758645 @default.
- W4281870178 cites W2583158609 @default.
- W4281870178 cites W2588227664 @default.
- W4281870178 cites W2765862270 @default.
- W4281870178 cites W2767213238 @default.
- W4281870178 cites W2767969468 @default.
- W4281870178 cites W2898237131 @default.
- W4281870178 cites W2910879530 @default.
- W4281870178 cites W2911951534 @default.
- W4281870178 cites W2911992229 @default.
- W4281870178 cites W2941719602 @default.
- W4281870178 cites W2944049918 @default.
- W4281870178 cites W2948804857 @default.
- W4281870178 cites W2950650328 @default.
- W4281870178 cites W2952025026 @default.
- W4281870178 cites W2987357836 @default.
- W4281870178 cites W2989424752 @default.
- W4281870178 cites W2996173585 @default.
- W4281870178 cites W3002425492 @default.
- W4281870178 cites W3007738297 @default.
- W4281870178 cites W3017009502 @default.
- W4281870178 cites W3024503671 @default.
- W4281870178 cites W3039247677 @default.
- W4281870178 cites W3086461097 @default.
- W4281870178 cites W3090555831 @default.
- W4281870178 cites W3098387594 @default.
- W4281870178 cites W3104722516 @default.
- W4281870178 cites W3118583114 @default.
- W4281870178 cites W3123030415 @default.
- W4281870178 cites W3125205294 @default.
- W4281870178 cites W3164454550 @default.
- W4281870178 cites W3172696365 @default.
- W4281870178 cites W3183956543 @default.
- W4281870178 cites W3194647262 @default.
- W4281870178 cites W4210698928 @default.
- W4281870178 cites W4214623514 @default.
- W4281870178 cites W4221080748 @default.
- W4281870178 cites W4230511297 @default.
- W4281870178 cites W4245086811 @default.
- W4281870178 cites W4251361927 @default.
- W4281870178 doi "https://doi.org/10.1002/chem.202201224" @default.
- W4281870178 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35652609" @default.
- W4281870178 hasPublicationYear "2022" @default.
- W4281870178 type Work @default.
- W4281870178 citedByCount "5" @default.
- W4281870178 countsByYear W42818701782023 @default.
- W4281870178 crossrefType "journal-article" @default.
- W4281870178 hasAuthorship W4281870178A5006345917 @default.
- W4281870178 hasAuthorship W4281870178A5010800024 @default.
- W4281870178 hasAuthorship W4281870178A5013572658 @default.
- W4281870178 hasAuthorship W4281870178A5027363854 @default.