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- W4281927528 abstract "Abstract Lithium metal batteries (LMBs) with extremely high energy densities have several advantages among energy storage equipment. However, the uncontrolled growth of dendrites and the flammable liquid electrolytes (LEs) often cause safety accidents. All solid‐state batteries seem to be the ultimate choice, but solvent‐free electrolytes usually fail in terms of conductivity at room temperature. Therefore, gel polymer electrolytes (GPEs) with a simple manufacturing process and high ionic conductivity are considered as the most competitive candidates to resolve the present difficulties. Herein, we design a polymeric network structure via esterification and amidation reactions between polyethylene glycol (PEG) and carbon dots (CDs). After incorporation with polyvinylidene fluoride and some LEs, the as‐prepared PEG–CDs composite electrolytes (PCCEs) show a high ionic conductivity of 5.5 mS/cm and an ion transference number of 0.71 at room temperature, as well as good flexibility and thermostability. When the PCCEs are assembled with lithium metal anodes and LiFePO 4 or LiCoO 2 cathodes, both the cycling stability and the retention rate of these LMBs show excellent performance at room temperature." @default.
- W4281927528 created "2022-06-13" @default.
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- W4281927528 date "2022-05-27" @default.
- W4281927528 modified "2023-10-17" @default.
- W4281927528 title "Carbon dots crosslinked gel polymer electrolytes for dendrite‐free and long‐cycle lithium metal batteries" @default.
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- W4281927528 doi "https://doi.org/10.1002/smm2.1121" @default.
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